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An electrochemical analysis of surface control (1988)

Bailey, J. M. ; Ritchie, I. M.

Springer

Oxidation of metals 30 (1988), S. 419-432

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ISSN: 1573-4889

Keywords: metal oxidation ; oxygen reduction

Source: Springer Online Journal Archives 1860-2000

Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract An electrochemical analysis of surface-controlled metal oxidation is presented. The reduction of molecular oxygen adsorbed on the oxide surface is broken into a number of steps. The possible rate-determining steps are analyzed in turn and the resultant rate equations derived. It is predicted that an Nth-root growth law will occur with N varying continuously over a limited range. A similar result for the pressure dependence of the oxidation rate is obtained.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00659009

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