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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 37 (1994), S. 23-34 
    ISSN: 1573-0867
    Keywords: aluminium ; Freundlich equation ; iron ; Langmuir equation ; phosphorus-32 ; P-sorption capacity ; Temkin equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Total amounts of phosphate (P) sorbed were measured for 6 Portuguese soils of widely varying properties.32P was used to assess the isotopically exchangeable and non-exchangeable sorbed P. Total sorbed and exchangeable P were described by modified Freundlich equations and non-exchangeable P by a Temkin equation. The Langmuir equation also proved to fit the data for non-exchangeable P well. The amount of total sorbed P required to attain 0.2 mg P 1−1 in solution ranged from 5.3 to 819 mg P kg−1. At this concentration exchangeable and non-exchangeable P values varied from 62.4 to 536.6 and from 0.4 to 322.1 mg P kg−1 respectively. There were highly significant (p 〈 0.01) correlations between soil organic matter and all forms of sorbed P (total sorbed, exchangeable and non-exchangeable). The P sorption parameters with correlation coefficients greater than 0.967 were parametersa andb of the modified Freundlich equation bn of Temkin and parametersa of the Langmuir equation. Aluminium extracted by acid oxalate (Alox) and dithionite (Aldi) showed highly significant correlation coefficients (r = 0.972) with the same sorption parameters. But P sorption was not closely related to the clay content Feox and Fedi. It was concluded that extractable aluminium (Alox and Aldi) had the most important effects on P sorption in these soils.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 34 (1993), S. 45-53 
    ISSN: 1573-0867
    Keywords: cation-anion-exchange resin ; fertilizer ; Olsen-P ; residual value ; phosphorus-32 ; sorghum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The amounts of available P in a Typic Pellustert containing different levels of residual fertilizer P were assessed in a field experiment and chemically with cation-anion-exchange resin, using: (i) P desorbed after 1 extraction, (ii) cumulative P from 8 extractions [Resin8-P] and (iii) the asymptote of the extraction curve. P exchangeable to32P, Olsen-P and P extracted by dilute salt solution (0.03M KCl) were also measured. P available to sorghum in 1989 was strongly influenced by fertilizer P applied in 1988, but not by P applied in 1987. Olsen-P and Resin8-P both reflected well the effects of residual P on yield and P uptake and could therefore be used to predict available residual P. The amounts of Resin8-P were much larger than Olsen-P, so it was easier to observe the differences between soil treatments, but Olsen-P gave the better correlations with grain yield and P uptake. Multiple regressions of crop yield or P uptake with amounts of P applied in 1987 and 1988 gave the best correlations, without the need for practical work. Thus, the development of an appropriate model based on records of P fertilization is seen as the most effective way to predict availability of residual P. Assessments related to the P intensity and desorption rate using resin were not able to improve predictions of available P, indicating that within one soil the quantity of residual P is most important, but for comparisons between soils, account will need to be taken of differences in soil characteristics.
    Type of Medium: Electronic Resource
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