ISSN:
0887-624X
Keywords:
polytrithiocarbonate
;
sulfur-containing polymer
;
phase-transfer catalyst
;
trithiocarbonate anion
;
two-phase reaction
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A series of aliphatic and aromatic polytrithiocarbonates was prepared using a novel “one-pot” synthesis procedure employing a phase-transfer catalyst. The starting reagents were either an aliphatic or an aromatic dihalide and an excessive amount of carbon disulfide. The effects of the phase-transfer catalyst and reaction conditions on yield were studied. The structure and composition of the polymers and reaction side-products were determined from infrared, ultraviolet, 1H-NMR spectra, and elemental analyses. The polymers were further characterized by viscosity measurement and thermal analysis. © 1993 John Wiley & Sons, Inc.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1993.080310719
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