ISSN:
1573-9171
Keywords:
radical pair
;
isotope effect
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A method for experimental testing of the molecular dynamic functionf(t), which describes the generation of reencounters in a dynamic pair of molecular particles, has been developed. The method is based on the analysis of isotope separation in spin selective reactions of a radical pair. Thef(t) function derived from the solution of the diffusion equation with physically rigorous initial and boundary conditions describes experimental results much better than the well-known Noyes function. Conditions that make it possible to increase the efficiency of isotope separation in spin selective reactions are formulated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01151272
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