ISSN:
1573-9171
Keywords:
linear organosilicon betaines
;
alkylidenephosphoranes
;
silanethione
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The title silanethione reacts with phosphorus ylides under conditions of kinetic control to give betaines containing a linear $$\begin{array}{*{20}c} \backslash \\ --- \\ / \\ \end{array} P^ + ---\begin{array}{*{20}c} | \\ C \\ | \\ \end{array} ---Si---S^ -$$ fragment. Under conditions of thermodynamic control, the derivatives of phosphonium 1-silaacenaphthene-1-thiolate are formed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00698899
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