ISSN:
0268-2605
Keywords:
ceramics
;
preceramic polymers
;
SiNCB composites
;
boron nitride
;
boron
;
silicon
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Our recent work directed at the design, synthesis, characterization and applications of new types of polyborazylene and polyborosilazane polymers is reviewed with a focus on the use of these polymers as processable precursors to BN and SiNCB composites. A design strategy based on the controlled functionalization of preformed polymers with pendant groups of suitable compositions and crosslinking properties has been employed to yield second-generation dipentylamine-polyborazylene (DPA) and pinacolborane-hydridopolysilazane (PIN-HPZ) polymers, which, unlike the parent polyborazylene (PB) and the borazine-hydridopolysilazane (B-HPZ) polymers, are stable as melts and can be easily melt-spun into polymer fibers. Subsequent pyrolyses of these polymer fibers then provide excellent routes to BN and SiNCB ceramic fibers. © 1998 John Wiley & Sons, Ltd.
Additional Material:
11 Ill.
Type of Medium:
Electronic Resource
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