ISSN:
1573-9171
Keywords:
carborane, thallium, mercury, complex
;
cyclopentadienylmanganese tricarbonyl
;
synthesis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The interaction of (CO)3MnC5H3RLi (R=2-Me2NCH2, H) with 2-Ph-1-HgBr-1, 2-C2B10H10 and (1, 7-C2H2B10H9-9)TlCl2 gives the corresponding C-carboranylmercury and B-carboranylthallium derivatives with M-C bonds, in which the C atom belongs to the cyclopentadienyl ring of the substituted cymantrenyl fragment. The structures of the compounds obtained are discussed on the basis of1H NMR and IR spectral data.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00698451
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