ISSN:
1573-9171
Keywords:
Organoaluminum compounds
;
organozirconium compounds
;
catalysts
;
olefins
;
magnesium
;
synthesis
;
hydrolysis
;
deuterolysis
;
alkoxides
;
aluminum chloride
;
amides
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A new stereoselective method is developed for the synthesis of 1-chloro-, 1-alkoxy-, and 1-N,N-dialkylaminoalumino-cyclopentanes from α-olefins, metallic magnesium, and aluminum halides (AlCl3, RO-AlCl2, R2N-AlCl2) in the presence of catalytic amounts of Cp2ZrCl2 (Cp=η5-C5H5). The products from hydrolysis and deuterolysis of the Al-substituted 3,4-dialkylaluminocyclopentanes (ACP) have the threo configuration.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00866593
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