ISSN:
1572-879X
Keywords:
aniline
;
dimethyl carbonate
;
alkylation
;
zeolite
;
EMT
;
beta
;
faujasite
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Zeolite K-EMT is as active and selective to N-mono methylation as K–Y in the alkylation of aniline with dimethyl carbonate at 408 or 453 K. No C-alkylation occurs in the temperature range studied. At 503 K, K-X and Cs-X are about 75% selective for dialkylation to N,N-dimethylaniline with about 97% conversion.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00817038
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