ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The structure of the polymeric rhodanine compound , C6H6CuIN2O2S4, was determined by X-rays.M r =456.8, monoclinic, space groupP21/c,a=4.1947(7),b=17.6999(12),c=17.1048(8) Å,β=96.15(1)°,V c =1262.6 Å3,Z=4,D c =2.40Mg m−3, CuKα radiation (graphite crystal monochromator, λ=1.54056 Å),μ(CuKα)=278.9 cms-1,F(000)=872,T=290 K. Final conventionalR-factor=0.029, andR w =0.044 for 2384 unique reflections and 153 variables. The structure was solved using Patterson methods andDirdif, and refined by full-matrix least-squares methods. The compound forms zigzag chains alonga. The copper atom is in trigonal pyramidal coordination, with two sulfur atoms of the thiocarbonyl group and two bridging iodine atoms. The copper-sulfur distances are 2.278(1) and 2.299(1) Å, and the copper-iodine distances are 2.657(1) and 2.814(1) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01566050
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