ISSN:
1573-935X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract We have studied the dependence of CIDNP effects on the concentration of the starting material in photolysis of a solution of benzaldehyde in cyclohexane-D12 and in benzene-D6. Using an excimer laser (λ=308 nm), we have investigated the time evolution of the CIDNP signals with time resolution 1 μsec. We have determined the rate constant k1′ for transfer of a hydrogen atom from the hydroxybenzyl radical to the ground-state benzaldehyde molecule and also the rate constant for recombination of two hydroxybenzene radicals.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00534558
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