ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Starting from optimal control, various series of infrared, ultrashort laser pulses with analytical shapes are designed in order to drive a preoriented molecule from its ground torsional state, which represents the coherent superposition of left and right atropisomers, towards a single enantiomer. Close analysis of the population dynamics, together with the underlying symmetry selection rules for the laser induced transitions, yields the mechanism. Namely, the molecule is driven from its ground vibrational state towards the coherent superposition of the lowest doublet of states via a doublet of excited torsional states with opposite symmetries. This pump-and-dump mechanism can be achieved by simpler series of analytical laser pulses. This decomposition of the optimal pulse into analytical subpulses allows us to design different scenarios for the selective preparation of left or right enantiomers. Exemplary this is demonstrated by quantum simulations of representative wave packets for the torsional motions of the model system, H2POSH, in the electronic ground state, based on the ab initio potential energy surface, and with ab initio dipole couplings. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1310595
Permalink
