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  • 11
    Electronic Resource
    Electronic Resource
    Zum relativen Donor-Akzeptor-Verhalten einzähniger Liganden. Eine EHT-Studie (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 577 (1989), S. 59-73 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Relative Donor-Acceptor-Properties of Monodentate Ligands. An EHT-StudyThe relative donor-acceptor properties of some important monodentate ligands are investigated by means of the extended Hückel method and a suitable graduation is determined. Charge gradations are discussed and results compared with known facts. Acceptor properties of ligands with phosphorous and sulfur atoms are described in the best manner using charge iterations at the atoms mentioned.
    Notes: Mit Hilfe der EHT-Methode werden die relativen Donor- und Akzeptor-Eigenschaften einiger wichtiger einzähniger Komplexliganden untersucht und eine entsprechende Abstufung ermittelt. Ladungsdifferenzierungen werden diskutiert und die Ergebnisse mit bekannten Erkenntnissen verglichen. Durch die Ladungsiteration an Phosphor- und Schwefelliganden lassen sich die Akzeptoreigenschaften dieser Moleküle relativ gut beschreiben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19895770107
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  • 12
    Electronic Resource
    Electronic Resource
    Schwefeldioxid als Ligand und Synthon. IX. Reaktionen von Cobaltcarbonylen mit Schwefeldioxid - Synthese und Charakterisierung von Alkoxysulfinyl-Cobaltcarbonyl-Komplexen (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 592 (1991), S. 141-152 
    Details
    ISSN: 0044-2313
    Keywords: Phosphine Cobalt Carbonyl Complexes ; Alkyl, Alkoxy Cobalt Carbonyls ; Sulfur Dioxide ; Organosilyl, Alkoxysulfinyl Phosphine Cobalt Carbonyl Complexes ; Synthesis ; IR, 1H NMR Spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfur Dioxide as Ligand and Synthon. IX. Reactions of Cobalt Carbonyls with Sulfur Dioxide - Synthesis and Characterization of Alkoxysulfinyl-Cobalt Carbonyl ComplexesReactions of phosphine substituted Co2(CO)8, (Ph2P-(CH2)n-PPh2: n = 1, dppm; n = 2, dppe; n = 3, dppp; n = 4, dppb), alkylcobalt carbonyls and alkoxycobalt carbonyls with sulfur dioxide have been investigated. The SO2 containing cobalt complexes are characterized by means of I.R., 1H-NMR, and mass spectra. Further on synthesis and properties of new alkoxysulfinylphosphine-cobalttricarbonyl complexes of the type ROS(O)Co(CO)3PR31 (R = Ph3Si, Me; R1 = Et, i-Pr, Ph) are described.
    Notes: Reaktionen von phosphinsubstituiertem Co2(CO)8, (Ph2P-(CH2)n-PPh2: n = 1, dppm; n = 2, dppe; n = 3, dppp; n = 4, dppb), Alkylcobaltcarbonylen sowie Alkoxycarbonyl-Cobaltcarbonylen mit Schwefeldioxid wurden untersucht. Die Charakterisierung der gebildeten SO2 enthaltenden Cobaltkomplexe erfolgte mit Hilfe der IR-, 1H-NMR- und Massenspektroskopie. Darüber hinaus werden Synthese und Eigenschaften neuer Alkoxysulfinyl-Phosphin-Cobalttricarbonyl-Komplexe des Typs ROS(O)Co(CO)3PR31 (R = Ph3Si, Me; R1 = Et, i-Pr, Ph) beschrieben.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19915920115
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  • 13
    Electronic Resource
    Electronic Resource
    Tris(triphenylphosphan)nickel(0)-Komplexe mit Nitril-Liganden (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1801-1805 
    Details
    ISSN: 0044-2313
    Keywords: Nickel complexes ; nitrile complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tris(triphenylphosphane)nickel(0) Complexes with Nitrile Ligands.Synthesis, properties and reaction behaviour of (Ph3P)3Ni(η1-NCR) (R = PhCH2, 2-MeC6H4, Me3Si) complexes as well as the X-ray structure of (Ph3P)3Ni(η1-NCSiMe3) are described. With NC(CH2)nBr (n = 1, 2) instead of the analogous nitrile complexes (Ph3P)2NiBr2 and CH3CN or C2H5CN respectively are formed.
    Notes: Synthese, Eigenschaften und Reaktionen der Komplexe (Ph3P)3Ni(η1-NCR) (R = PhCH2, 2-MeC6H4, Me3Si) sowie die Kristallstruktur von (Ph3P)3Ni(η1-NCSiMe3) werden beschrieben. Mit NC(CH2)nBr (n = 1, 2) entstehen nicht die analogen Nitril-Komplexe sondern (Ph3P)2NiBr2 und CH3CN bzw. C2H5CN.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936191029
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  • 14
    Electronic Resource
    Electronic Resource
    Schwefeldioxid als Ligand und Synthon. XII. Synthese und Reaktivität von Nickel(II)-Komplexen dreizähniger anionischer Liganden des Typs (C6H3{CH2NR1R2}2-2,6)- (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1931-1938 
    Details
    ISSN: 0044-2313
    Keywords: Organonickel(II) complexes ; SO2 coordination ; IR photoacoustic spectroscopy ; X-ray crystal structure of [NiBr{C6H3(CH2NR1R2)2-2,6}] ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfur Dioxide as Ligand and Synthon. XII. Synthesis and Reaction Behaviour of Nickel(II) Complexes with Terdendate Anionic Ligands of the Type (C6H3{CH2NR1R2}2-2,6)-Organonickel(II) complexes of the type [NiX{C6H3(CH2NR1R2)2-2,6}] (X = halide OH2+/CF3SO3-; R1=R2=Et 1; R1=R2=i—Pr 2; R1 = Me, R2 = Cy 3; (NR1R2) = piperidino 4; (NR1R2) = pyrrolidino 5) are described. 1H and 13C NMR and UV/Vis spectra were recorded, and the X-ray crystal structure of 1 a (X = Br) was determined. This complex crystallizes orthorhombically in the space group Pbca with a = 1 335.8(2) pm, b = 1 903.3(3) pm, c = 1 365.4(3) pm and Z = 8, and has an approximately square-planar geometry. 4 and 5 show a reversible binding of SO2 which has been detected by means of IR photoacoustic spectroscopy. The reactions of 1-5 with CS2 and PhNSO are discussed.
    Notes: Organonickel(II)-Komplexe des Typs [NiX{C6H3(CH2NR1R2)2-2,6}] (X = Halogen, OH2+/CF3SO3-; R1=R2=Et 1; R1=R2=i—Pr 2; R1 = Me, R2 = Cy 3; (NR1R2) = piperidino 4; (NR1R2) = pyrrolidino 5) werden beschrieben. Die Charakterisierung erfolgte mit Hilfe der 1H— und 13C-NMR- sowie der UV/Vis-Spektroskopie. Von 1 a (X = Br) wurde die Kristallstruktur bestimmt. Dieser Komplex kristallisiert orthorhombisch in der Raumgruppe Pbca mit a = 1 335,8(2) pm, b = 1 903,3(3) pm, c = 1 365,4(3) pm und Z = 8, er besitzt eine annähernd quadratisch-planare Geometrie. 4 und 5 vermögen SO2 reversibel zu fixieren, was durch die IR-Photoakustik-Spektroskopie nachweisbar ist. Die Reaktionen von 1-5 mit CS2 und PhNSO werden diskutiert.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936191118
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  • 15
    Electronic Resource
    Electronic Resource
    Triphenylphosphan-Nickel(0)-Komplexe mit Isocyanid-Liganden  -  [(RNC)nNi(PPh3)4-n] (n = 1-3)Professor Kurt Issleib in memoriam (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 2048-2052 
    Details
    ISSN: 0044-2313
    Keywords: Nickel(0) complexes ; isocyanide ligands ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Triphenylphosphane Nickel(0) Complexes with Isocyanide Ligands  -  [(RNC)nNi(PPh3)4-n] (n = 1-3)Synthesis and properties of the isocyanide triphenylphosphane nickel(0) complexes [(RNC)Ni(PPh3)3], [(RNC)2Ni(PPh3)2] and [(RNC)3Ni(PPh3)] (R = tBu, Cy, PhCH2, p-TosCH2) are described. I.r. and 31P n.m.r. spectra were recorded and the X-ray crystal structure of [(PhCH2NC)2Ni(PPh3)2] was determined.
    Notes: Synthese und Eigenschaften von Isocyanid-Triphenylphosphan-Nickel(0)-Komplexen der Typen [(RNC)Ni(PPh3)3], [(RNC)2Ni(PPh3)2] und [(RNC)3Ni(PPh3)] (R = tBu, Cy, PhCH2, p-TosCH2) werden beschrieben.Die Charakterisierung der genannten Komplexe erfolgte mit Hilfe der IR- und 31P-NMR-Spektroskopie, von [(PhCH2NC)2Ni(PPh3)2] wurde die Molekülstruktur bestimmt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946201206
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  • 16
    Electronic Resource
    Electronic Resource
    Schwefeldioxid als Ligand und Synthon. XIII. Reaktionen von Isocyanid-tris(triphenylphosphan)nickel(0)-Komplexen mit Schwefeldioxid und N-p-Tolylsulfinylamin (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 2114-2120 
    Details
    ISSN: 0044-2313
    Keywords: Nickel(0) complexes ; sulfur dioxide complexes ; N-p-tolylsulfinylamine complexes ; isocyanide ligands ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfur Dioxide as Ligand and Synthon. XIII. Reactions of Isocyanide-tris(triphenylphosphane)nickel(0) Complexes with Sulfur Dioxide and N-p-tolylsulfinylamineReactions of the isocyanide-tris(triphenylphosphane)-nickel(0) complexes [(RNC)Ni(PPh3)3] (R = tBu, Cy, PhCH2, p-TosCH2) with SO2 and p-TolNSO are described. The sulfur dioxide and N-p-tolylsulfinylamine complexes obtained by PPh3 ligand substitution have been characterized by means of i.r. and 31P n.m.r. spectra. The X-ray crystal structure of [(Ph3P)2(CyNC)Ni(SO2)] · 0.5 PhMe and (Ph3P)(tBuNC)Ni(η2-p-TolNSO) have been determined.
    Notes: Reaktionen der Isocyanid-tris(triphenylphosphan)-nickel(0)-Komplexe [(RNC)Ni(PPh3)3] (R = tBu, Cy, PhCH2, p-TosCH2) mit SO2 und p-TolNSO werden beschrieben. Die Charakterisierung der durch PPh3-Ligandensubstitution resultierenden Schwefeldioxid- sowie N-p-Tolylsulfinylamin-Komplexe erfolgte mit Hilfe der IR- und 31P-NMR-Spektroskopie. Für [(Ph3P)2(CyNC)Ni(SO2)] · 0,5 PhMe und (Ph3P) · (tBuNC)Ni(η2-p-TolNSO) wurden die Kristallstrukturen bestimmt.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946201215
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  • 17
    Electronic Resource
    Electronic Resource
    1,4-Diazabuta-1,3-dien-N-Sulfinylamin-Nickel(0)-Komplexe (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 926-930 
    Details
    ISSN: 0044-2313
    Keywords: Nickel(0) complexes ; 1,4-diazabuta-1,3-diene ; N-sulfinylamine ligands ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 1,4-Diazabuta-1,3-Diene-N-Sulfinylamin Nickel(0) ComplexesSynthesis, properties, and reactions of 1,4-diazabuta-1,3-diene-N-sulfinylamine nickel(0) complexes are described. The highly coloured and extremely air and moisture sensitive nickel(0) complexes have been characterized by means of i.r. and 1H n.m.r.spectroscopy. The N-sulfinylamine ligands are η2-(S,N)-side on coordinated.
    Notes: Synthese, Eigenschaften und Reaktionen von 1,4-Diazabuta-1,3-dien-N-sulfinylamin-nickel(0)-Komplexen des Typs Ni(DAB)(RNSO) (R = Ph, p-Tol, Cy) werden beschrieben. Die Charakterisierung der diamagnetischen, intensiv farbigen und extrem oxidations- und feuchtigkeitsempfindlichen Nickel(0)-Komplexe erfolgte mit Hilfe der IR- und 1H-NMR-Spektroskopie. Die N-Sulfinylamin-Liganden sind η2-(S,N)-side on koordiniert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946200528
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  • 18
    Electronic Resource
    Electronic Resource
    Bis(diphenylphosphano)alkan- und 1-(Diphenylphosphano)-2-(2-pyridino)ethan-N-Arylsulfinylamin-Nickel(0)-Komplexe (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 435-438 
    Details
    ISSN: 0044-2313
    Keywords: Nickel(0) complexes ; diphenylphosphanoalkane ; 1-diphenylphosphano-2-(2-pyridino)ethane ; N-arylsulfinylamine ligands ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bis(diphenylphosphano)alkane- and 1-Diphenylphosphano-2-(2-pyridino)ethane-N-arylsulfinylamine Nickel(0) ComplexesSynthesis and properties of the bis(diphenylphosphano)alkane-N-phenyl-sulfinylamine-nickel(0) complexes [Ni{Ph2P(CH2)nPPh2}(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) as well as of the 1-(diphenylphosphano)-2-(2-pyridino)ethane nickel(0) complexes [Ni(dpppe)2], [Ni(dpppe)(p-TolNSO)] and [Ni(dpppe)(PPh3)2] are described.These compounds have been characterized by i. r. and 31P n.m.r. spectroscopy. The N-arylsulfinylamine ligands are η2-(N, S)-side on coordinated.
    Notes: Synthese und Eigenschaften der Bis(diphenylphosphano)alkan-N-Phenylsulfinylamin-Nickel(0)-Komplexe [Ni{Ph2P(CH2)nPPh2}(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) sowie der 1-Diphenylphosphano-2-(2-pyridino)ethan-Nickel(0)-Komplexe [Ni(dpppe)2], [Ni(dpppe)(p-TolNSO)] und [Ni(dpppe)(PPh3)2] werden beschrieben.Die Charakterisierung der genannten Verbindungen erfolgte mit Hilfe der IR- und 31P-NMR-Spektroskopie. Die N-Arylsulfinylamin-Liganden sind η2-(N, S)-side on koordiniert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210317
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  • 19
    Electronic Resource
    Electronic Resource
    Schwefeldioxid als Ligand und Synthon. V. Ni(PMe2Ph)3(SO2) - ein Nickel(0)-Komplex mit η1-pyramidal koordiniertem SO2 (1987)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 549 (1987), S. 171-176 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfurdioxide as Ligand and Synton. V. Ni(PMe2Ph)3(SO2) - a Nickel(0) Complex with η1-pyramidal Coordinated SO2Ni(PMe2Ph)3(SO2) was synthesized by reaction of SO2 with a solution of Ni(COD)2 and PMe2Ph in tetrahydrofuran. The compound crystallizes cubically in the space group Pa3 with a = 17.991 Å and Z = 8. For the first time a pyramidal coordination of SO2 was found for a complex of the composition NiL3(SO2). The most important structural parameters are: Ni—S 2.001 Å, Ni—P 2.002 Å, S—O 1.451 Å, and the bond angle O—S—O 92.6°.
    Notes: Ni(PMe2Ph)3(SO2) wurde synthetisiert durch Reaktion von SO2 mit Ni(COD)2 und PMe2Ph in einer Lösung von THF. Die Verbindung kristallisiert kubisch in der Raumgruppe Pa3 mit a = 17,991 Å und Z = 8. Erstmalig wurde in einem Komplex der Zusammensetzung NiL3(SO2) eine pyramidale Koordination des SO2 gefunden. Die wichtigsten Strukturparameter sind: Ni—S 2,001 Å, Ni—P 2,002 Å, S—O 1,451 Å und der Bindungswinkel O—S—O 92,6°.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19875490617
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  • 20
    Electronic Resource
    Electronic Resource
    Schwefeldioxid als Ligand und Synthon. VIII. Zum Einfluß der Coliganden auf die Koordinationsgeometrie von SO2 in Nickel(O)-Komplexen - Eine EHT-StudieProfessor Kurt Issleib zum 70. Geburtstage am 19. November 1989 gewidmet (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 578 (1989), S. 37-46 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfur Dioxide as Ligand and Synton. VIII. On the Influence of Coligands on the Coordination Mode of SO2 in Nickel(O) Complexes. An EHT StudyThe dependence of the sulfur dioxide coordination mode in NiL3(SO2) complexes has been investigated in terms of the nature of the coligands L = PF3, CO, CNMe, PH3 and PMe3 by means of the extended Hückel theory. For PF3, CO, CNMe the planar coordination mode should be favoured while PH3 and PMe3 compounds should contain pyramidal bonded sulfur dioxide. Charge and bond-strength gradations are discussed.
    Notes: Die Abhängigkeit der SO2-Koordinationsgeometrie in Komplexen des Typs NiL3(SO2) von der Natur der Coliganden L = PF3, CO, CNMe, PH3 und PMe3 wurde mit Hilfe der erweiterten Hückel-Theorie untersucht. Demzufolge sollte im Falle von CO, PF3 und CNMe die planare, dagegen für PH3 und PMe3 die pyramidale SO2-Koordination bevorzugt sein. Ladungs- und Bindungsstärkeabstufungen werden diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19895780105
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