ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Vincetene, a Benzopyrroloisoquinoline Alkaloid, from Cynanchum Vincetoxicum (L.) Pers. (Asclepiadaceae)Cynanchum vincetoxicum contains traces of an alkaloid C22H27NO3, whose structure has been shown to be 6-(3-hydroxy-cis-1-butenyl)-2,3-dimethoxy-7,9,10,11,11a,12-hexahydrobenzo[f]-pyrrolo[1,2-6]isoquinoline (2) and has been confirmed by synthesis of the rac-dihydrodesoxy-derivative 18.
Notes:
Cynanchum vincetoxicum (L.) Pers. enthält Spuren eines Alkaloids C22H27NO3, dessen Struktur als 6-(3-Hydroxy-cis-1-butenyl)-2,3-dimethoxy-7,9,10,11,11a, 12-hexahydrobenzo[f]pyrrolo[1,2-b]-isochinolin (2) geklärt und durch Synthese des rac-Dihydrodesoxy-Derivates 18 gesichert wurde.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.197919790815
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