ISSN:
0009-2940
Keywords:
Nickel Schiff base complexes
;
Base adducts
;
Chirality
;
Steric hindrance
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of the ligand meso-H2L, derived from cis-diaminocyclohexane and ethyl cyano(ethoxymethylene)acetate, with nickel(II) acetate gives meso-NiL. Spectrophotometric titration of RR-NiL and meso-NiL with various nitrogen bases reveals a strong influence of the steric hindrance of the diaminocyclohexanediyl bridge in meso-NiL on the base adduct stability. The structures of RR-NiL and meso-NIL have been established by X-ray diffraction.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971301114
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