Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
18 (1986), S. 829-836
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The thermal decomposition of diethyl ether was studied in the temperature range 697.2-760.5 K. The rate constant of reaction (1), and the ratio of the rate constant of reaction (2) to that of (12): were calculated from the amounts of products: \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_1 ({\rm s}^{{\rm - 1}}) = (17.2 \pm 0.6) - (82.4 \pm 2.0{\rm kcal mol}^{{\rm - 1}})/2.3RT $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_2 /k_{12^{1/2} } ({\rm dm}^{{\rm 3/2}} {\rm mol}^{{\rm - 1/2}}) = (4.1 \pm 0.4) - (11.9 \pm 1.3{\rm kcal mol}^{{\rm - 1}})/2.3RT $$\end{document}
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180803
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