ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
In the title compound, [Pd(C6H5)(C10H11O2S)(C18H15P)]·C4H8O, an isopropylthiobenzoate ligand is coordinated in a bidentate fashion to the central Pd atom through the O and S atoms. The square-planar geometry of the Pd atom is completed by a phenyl ligand and a triphenylphosphine group but is distorted by the bidentate ligand, which forms a six-membered chelate ring. This ring deviates strongly from planarity, which is illustrated by the plane through the phenyl portion of the chelate ring forming a dihedral angle of 62.3 (1)° with the coordination plane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270199016480
Permalink