ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the gas-phase decomposition of 1,2-epoxycyclohexane has been studied over the temperature range 680-740 K at pressures between 1.6 and 6 torr. Isomerization to cyclohexanone and 2-cyclohexen-1-ol accounts for ca. 97% of the primary reaction products and occurs by first-order, homogeneous, nonradical processes: \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{cyclohexanone} /s^{ - 1} = 10^{14.58 \pm 0.35} \exp \left( { - 60,300 \pm 1,100/1.987T} \right) $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{cyclohexanone - 1 - o1} /s^{ - 1} = 10^{13.11 \pm .41} \exp \left( { - 55,800 \pm 1,300/1.987T} \right) $$\end{document}
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550050306
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