ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The mass spectra of thirty sydnoes have been interpreted; the types investigated include 3-aryl, 3-alkyl-, substituted 3-alkylsydnones; and bis sydnones. A characteristic fragmentation mode involves initial loss of NO and CO from the molecular ion, but peaks corresponding to alkylcarbonium ions dominate the spectra of 3-alkylsydnones; a cyclic mechanism is suggested for weak transitions involving loss of sydnone neutral molecule from the molecular ion. A mechanism is proposed for loss of chlorine radical from the molecular ion of 3-(2,4-dichlorophenethyl)sydnone. An unusual feature in the mass spectrum of trimethylenebis sydnone is rationalised on the basis of a precursor 1,2,3-oxadiazole ion. The effect of substituents in the aryl ring on the fragmentation of 3-arylsydnones is discussed.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210021004
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