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  • 1
    Electronic Resource
    Electronic Resource
    Lipase catalyzed transesterification of 2-substituted 3-hydroxy esters (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Chirality 10 (1998), S. 693-698 
    Details
    ISSN: 0899-0042
    Keywords: Pseudomonas cepacia ; lipase PS ; transesterification ; kinetic resolution ; 2-substituted 3-hydroxy ester ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic resolution of 2-substituted 3-hydroxy esters was examined by lipase PS catalyzed transesterification using vinyl acetate as an acyl donor. Resolution of (±)-syn- and -anti-1a, -1e possessing a small methyl group at the C-3 position was accomplished enantioselectively. The outcome of the resolution seems to be related to the differences in size of the substituents at the stereocenter bearing a secondary hydroxy group. Chirality 10:693-698, 1998. © 1998 Wiley-Liss, Inc.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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