ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Copper(II) salts react with benzenecarbothioamide(BCTA);N,N-dimethylbencenecarbothioamide (DMBCTA) andN,N-diethylbenzenecarbothioamide (DEBCTA) to give complexes with 1∶1, 2∶1, 3∶1 ligand/metal stoichiometric ratios, and a diamagnetic complex [Cu2(DEBCTA)Br4]2 which appears to contains copper(I). These compounds were characterized by elemental analyses, conductivities measurements, i.r., electronic and e.p.r. studies and magnetic measurements. The results suggest tetrahedral geometry for the copper(II) complexes, a dimeric structure for bromide-DMBCTA and chloride and bromide-BCTA derivatives, and a square pyramid geometry for the CuBr2-DEBCTA complex. No information is yet available on the coordination geometry of the copper(I) complex.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01225133
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