ISSN:
1434-1948
Keywords:
Dimolybdenum(III) complexes
;
Azavinylidene
;
C-C coupling
;
Acetonitrile ligands
;
X-ray crystal structure
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Removal of a proton from one of the two coordinated acetonitrile ligands in [Mo2Cp2(μ-SMe)3(CH3CN)2](BF4) (1) initiates its intramolecular condensation with the second of the acetonitrile ligands attached to the bimetallic [Mo2Cp2(μ-SMe)3] core, thereby giving rise to the novel μ-η1-azavinylidene complex {Mo2Cp2(μ-SMe)3[μ-η1-N=C(CH3)-CH2CN]} (2). Complex 2 has been characterized by NMR and X-ray methods.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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