ISSN:
1573-1561
Schlagwort(e):
Enantiospecific
;
synthesis
;
spiroacetal
;
pheromone
;
olive fruit fly
;
d-Fructose
;
Dacus oleae
;
Diptera
;
Tephritidae
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Biologie
,
Chemie und Pharmazie
Notizen:
Abstract The synthesis of the title compound13 has been carried out through the preparation of its precursor, (3R,4R,5S,6R)-3,4,5-trihydroxy-1,7-dioxaspiro[5.5]undecane (6), obtained fromd-fructose using Wittig's methodology, reduction, and spiroketalation. Compound6 was transformed into13 by a Barton deoxygenation at C-5 followed by a Corey dideoxygenation at C-3,4 of the appropriately protected derivatives.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00984686
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