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A generalized hard-sphere augmented virial equation of state (1973)

Bienkowski, Paul R. ; Denenholz, Howard S. ; Chao, Kwang-Chu

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 19 (1973), S. 167-173

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Details

ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: A generalized equation of state is developed by combinin a hard-sphere equation with a truncated virial equation and generalizing the reduced hard-sphere diameter as a function of reduced temperature and acentric factor. The new equation quantitatively agrees with Pitzer's table of compressibility factor over wide ranges of gas and vapor states and is always better than the truncated virial equation. Since the terms in the equation are physically meaningful it is capable of being improved systematically by including higher virial coefficients and by using hard-core equations of state for nonspherical cores. The equation is extended to mixtures with well-developed combination rules.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690190124

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