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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Macromolecules 4 (1971), S. 134-138 
    ISSN: 1520-5835
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 10 (1972), S. 2223-2229 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Specific heats of a series of plasticized and unplasticized poly(vinyl chloride) compositions have been determined by a differential scanning calorimeter over the temperature range 200-400°K. The glass temperatures were higher and the specific heat values at 300°K lower with phthalate esters then with esters of aliphatic acids; those values were also higher and lower, respectively, with benzyl-containing esters than with the methyl or octyl esters. The data were treated by a computer technique and plotted. A mathematical expression was developed which would describe the curves obtained when specific heat was plotted against temperature, and provided values in each case for the glass temperature and the specific heat at the glass temperature and at 300°K, as well as other descriptive parameters.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 3139-3150 
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This thermal degradation study reports the application of “time-resolved” pyrolysis gas chromatography (PGC) in addition to derivative thermogravimetric analysis (DTGA) to a series of PVC homopolymers with differing branch content and to a model copolymer series with low amounts of propylene in an otherwise vinyl chloride chain. Benzene and toluene generation and decay envelopes were determined during the controlled thermal degradation and related to the derivative TGA experiments. These data allowed interpretation as to the microstructure of the respective polymers and its effect on the degradative pathways. It was concluded that the branch content was not a dominant factor in the initiation of thermal degradation, although it was a factor in other stages of the complex mechanism. A unique fragmentation step was noted only under oxidative thermal exposures, which gave additional support for the theory of low-level unsaturation sites as being significant triggers in the decomposition mechanism.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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