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Digitale Medien

Structure of confined alkane liquids (1994)

Walley, K. P. ; Schweizer, K. S. ; Peanasky, J. ; [weitere]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 100 (1994), S. 3361-3364

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ISSN: 1089-7690

Quelle: AIP Digital Archive

Thema: Physik , Chemie und Pharmazie

Notizen: Polymer integral equation theory is employed to calculate structural properties of undecane and short polymer liquids confined between parallel plates. A strong dependence is found on the strength of fluid–surface interactions which is consistent with solvation force measurements using both strongly attractive mica and weakly repulsive hydrocarbon surfaces.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1063/1.466377

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Digitale Medien

Surface synthesis of thiophene (1989)

Gentle, T. M. ; Tsai, C. T. ; Walley, K. P. ; [weitere]

Springer

Catalysis letters 2 (1989), S. 19-26

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ISSN: 1572-879X

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract A cyclization reaction has been observed in which thiophene is produced from acetylene and sulfur co-adsorbed on the Pd(111) surface. As in the case of acetylene trimerization to benzene the reaction yielding thiophene can proceed via an intermediate species of stoichiometry C4H4. The ability of the reaction intermediate to extract sulfur from the surface varies between the two phases of adsorbed sulfur that can exist on the Pd(111) surface.