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Volumetric properties of mixtures of water and methanol H/D-isotopomers between 5 and 45°C (1996)

Ivanov, E. V. ; Abrossimov, V. X.

Springer

Journal of solution chemistry 25 (1996), S. 191-201

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ISSN: 1572-8927

Keywords: Solvent isotope effects ; methanols ; H/D-isotopomers ; aqueous solutions ; volumetric properties

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Densities of H/D-isotopomers mixtures of water (H2O, D2O) and methanol (CH3OH, CD3OH, CH3OD, and CD3OD) over the full range of compositions were measured at 5, 15, 25, 35, and 45°C. Results have been used to calculate molar volumes, excess molar volumes, apparent molar volumes, and isotope effects of the mixtures. The volumetric properties are discussed in terms of the structural changes in water-methanol solutions under the influence of isotope substitution.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00972689

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