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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 2913-2921 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The characteristics of various cw mode-locked dye lasers were thoroughly explored, and the characteristics of a pump/probe apparatus employing two such lasers pumped by a single mode-locked pump laser. First, it was observed that the rf source used to drive the acousto-optic mode-locking element in the pump laser, while not affecting the average power or obtainable pulse width, had a profound effect on the noise characteristics of the pump laser, which are in turn passed along to the dye lasers. For a driver based on a tunable frequency synthesizer, pulse jitter on the order of 300 ps was observed, which represents ≈2.5% of the total interpulse time interval. This was deemed unacceptably high, and use of this mode-locker driver was discontinued. For a driver with a fixed frequency reference source (an oscillating quartz crystal), pulse jitter on the order of 5 ps was measured, a great improvement over the other driver. Next we studied various dye laser configurations pumped by this pump laser. We found that for time resolution of several picoseconds, a pair of synchronously pumped dye lasers employing birefringent filter tuning elements was an excellent source of independently tunable pulse trains, and that these pulse trains were well synchronized with each other despite the absolute timing jitter in the pump pulse train. To obtain better temporal resolution with independently tunable lasers was more problematic, however. A hybridly mode-locked laser (employing a saturable absorber within a synchronously pumped dye laser) can produce shorter pulses (≤100 fs has been reported), but the lack of temporal synchronization between two of these lasers limits the resolution of a two wavelength experiment to several picoseconds. An attempt was made to reduce this relative timing jitter by crossing two independently tunable hybrid lasers through a common intracavity saturable absorber, thereby temporally locking the pulse trains together. This mechanism failed to work well on time scales longer than a millisecond.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 3580-3581 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 4055-4066 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Polarization spectroscopy has been developed as a useful method for the investigation of molecular reorientation in both liquid phase solutions and in the gas phase. This technique has the advantage of measuring a single particle orientational correlation function directly but the disadvantage of averaging over rotation in all electronic states. Described and characterized herein is a variant of this technique, optically heterodyned polarization spectroscopy, which is able to disentangle various contributions to the signal and determine the rotational relaxation of the solute molecule in different electronic states independently. This work also demonstrates the measurement of the normalized value of the orientational correlation function at time zero, r(0), without extensive normalization of laser parameters. Lastly, various technical advantages of the optically heterodyned method are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 6770-6783 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational diffusion of three mechanically similar phenoxazine dyes possessing distinct electrical properties was studied in isopropanol. The results, along with previously presented results from other polar solvents, were analyzed in terms of continuum theories for rotational dielectric friction. It was found that a continuum based theory can account for the observed rotational relaxation dynamics, but only with realistic modeling of the solute charge distribution (not a point dipole), and by accounting for both frequency and wave vector dependences of the solvent dielectric properties.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 6196-6202 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The dielectric friction on a solute molecule reorienting in a liquid solution is computed by modeling the solute as a rigid collection of point charges rotating within a spherical cavity in a dielectric continuum. Such a calculation on an extended charge distribution is a logical progression from existing theories, which treat only single point charges or point dipoles. It is shown how a more realistic charge distribution can change the calculated friction coefficient by several orders of magnitude, and the generalized theory is applied to rotational diffusion data for three phenoxazine dyes in dimethylsulfoxide.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 4509-4520 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rotational diffusion times for three mechanically similar phenoxazine dyes with differing electronic properties were measured. These studies probe the importance of dipole/dipole and ion/dipole couplings to the friction. The experimental results are compared with the predictions of available continuum theories of dielectric friction. Future directions for a more realistic model of dielectric friction are discussed.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 95 (1991), S. 4848-4852 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 95 (1991), S. 7872-7880 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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