ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the oxidation of thiosulfate ion by [Mn(Y)]- (H4Y = trans-cyclohezane-1,2-dimine-N,N,N′,N′-tetraacetic acid) and [Ni(L1)]2+ (HL1 = 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) have been investigated at 20.0, 30.0, and 40.0°C in aqueous solution and found to follow the general rate law -d/dt [complex] = kox[S2O32-] [complex]. The large negative entropy (ΔS
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550270704
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