ISSN:
1573-9171
Keywords:
CH-acids fluorinated
;
[3,3]-sigmatropic rearrangement
;
2-alkenyl-2-tri-fluoromethylmalonates
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract CH-acids of general formula CF3CH(X)CF3 (X = CF3, CO2R) react with 2,3-unsaturated alcohols in the presence of bases to give trifluoromethylated products of the [3,3]-sigmatropic rearrangement. These reactions provide a convenient method for the synthesis of 2-alkenyl-2-trifluoromethylmalonates.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00698247
Permalink