ISSN:
1572-8927
Keywords:
Mixed metal complexes
;
hydrocarboxylic acids
;
spectrophotometry
;
complex stoichiometry
;
aqueous solutions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The formation of mixed metal complexes between uranium (VI), as the central metal ion, and aluminium (III), indium (III), copper (II), zinc (II) and cadmium (II), as the additional metal ions, with a hydroxycarboxylic acid chosen between citric, tartaric or malic, has been studied using spectrophotometric methods. The effect of pH has been examined, and the results show that at pH=4 stable complexes are formed for most of the systems. At this pH the method of mole ratio and Job's method of continuous variations, were employed to determine the stoichiometry of the mixed metal complexes. Al(III), In(III) and Cu(II) showed a high tendency to form mixed metal complexes with U(VI), while the formation of complexes is uncertain for Cd(II) and Zn(II). The ratio of the ligand to the total metal ion has been found to be 2∶1 and metal:metal ratios of 1∶1 and 1∶2 have been observed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00651852
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