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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Psychosomatic Research 25 (1981), S. 33-41 
    ISSN: 0022-3999
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Medicine , Psychology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Recycling of polyethyleneterephthalate (PET) bottles for soft drinks is accomplished by depolymerization through glycolysis. Obtained intermediates are reacted with mixtures of saturated and unsaturated acids to obtain unsaturated polyesters (UP) suitable for use as a matrix for fibre-reinforced thermosetting composites. The influence of chemical structure of glycols on the chemo-rheological behaviour of resins, has been verified. By using di-ethylene glycol, the behaviour of the resulting UP closely resembles that of UP obtained from virgin monomers. Moreover, composite sheets containing UP developed in the present research, show enhanced toughness if compared with the analogous composite made of virgin UP resin.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract With the aim of exploring possible application of the concept of blend compatibilisation into the field of biodegradable membranes, a study of the influence of random copolymer poly(D,L-lactide-co-∈-caprolactone) on the properties of corresponding homopolymer blends has been conducted. Blends of plain homopolymers and blends containing 5 and 10 wt% of a copolymer of suitable composition have been prepared in the melt and characterised for their molecular interactions using thermal, dynamic-mechanical, mechanical (tensile tests) and morphological analyses. The blends are characterised by a good dispersion of the poly-∈-caprolactone (PCL) minor phase into the poly(D,L-lactic acid) (PDLLA) matrix and better mechanical properties compared to plain PDLLA, and such characteristics further improve when adding the copolymer. Microporous blend membranes consisting of PDLLA and PCL were then prepared by a phase inversion method and characterised by scanning electron microscopy. The addition of compatibilising agent led to a highly homogeneous structure, while in absence of compatibiliser a clear phase separation occurred.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 214 (1994), S. 101-113 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Polyhydrazid/Polyamid-Blends (PEHZ12/PA6) wurden durch Niedrigtemperatur-Polykondensation von 4,4′-Dichlorformyl-α,ω-diphenoxydodecan und Terephthaloyldihydrazid (TDH) zu Poly(etheraroylhydrazid) in Gegenwart von Polyamid 6 synthetisiert. Die DSC-Analysen lassen vermuten, daß die zwei Polymerkomponenten nicht wechselwirken. Bei der Extraktion des PA6-Anteils der Blends mit Ameisensäure zeigt die Charakterisierung des PEHZ12-Extraktionsrückstands aber, daß zumindest bei bestimmten Zusammensetzungen Wechselwirkungen zwischen den Komponenten auftreten. Modellreaktionen erlauben die Annahme, daß die PEHZ12-Polymerisation zwischen den Amino-Endgruppen des PA6 und den wachsenden PEHZ12-Polymerketten abläuft.
    Notes: Poly(etheraroylhydrazide) is synthesized in the presence of PA6 by means of low-temperature condensation polymerization of 4,4′-dichloroformyl-α,ω-diphenoxydodecane with terephthaloyl dihydrazide (TDH) in order to prepare polyhydrazide/poly-amide 6 (PEHZ12/PA6) blends. The thermal analysis of the blends by DSC seems to indicate that the two polymers are not interacting. Nevertheless, when the blends are subjected to an extraction process with formic acid in order to remove the PA6, the characterization of the residual PEHZ12 reveales that some interactions do occur between the constituent polymers, at least for selected compositions. Model experiments permit to hypothesize that the polymerization of PEHZ12 proceeds with a chemical interaction between amino end groups of PA6 and growing PEHZ12 chains.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 1747-1752 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mixtures of PET and PVC were prepared in three different compositions by a solution blending technique. A plasma surface modification method was applied to PET powder surfaces in order to enhance the miscibility of both components because of their mutual insolubility. The intrinsic viscosities of blends were measured in a phenol/tetrachloroethanemixed solvent system. The degree of compatibility of blends was characterized by the use of the parameter Δb, as derived by Krigbaum and Wall. © 1993 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 57-67 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Influence of spinning velocities on the mechanical and structural properties of polyethylene terephthalate (PET)/nylon 6 blend fibers have been reported. Fibers of PET/nylon 6 containing a small percentage of nylon (5% by weight) have been melt-spun at 3 different spinning velocities (2,900; 3,200; 3,600 m/min). The fibers have been characterized by thermal, morphological, structrual, and mechanical analysis. Various techniques such as SEM, DSC, X-ray diffraction, hot water shrinkage (HWS), viscosity, and birefringence have been used. SEM analysis revealed that in the blend, nylon 6 is well-dispersed as spheres in the PET matrix. The blend shows a marked decrease in the melt-flow index, which in turn leads to a beneficial effect on the rheological properties of the PET without negatively influencing its mechanical characteristics. This finding results in a saving on energetical requirements of the processing, as both temperature and pressure of spinning can be decreased. © 1995 John Wiley & Sons, Inc.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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