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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 81 (1969), S. 485-493 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Silylene werden ähnlich wie Carbene bei vielen Reaktionen als Zwischenstufen angenommen. Neben den reduktiven und thermolytischen Darstellungsmethoden wird das reaktive Verhalten dieser Spezies ausführlich behandelt; Einschiebungs- und Abfangreaktionen betonen die formale Verwandtschaft zu den Carbenen. Die Isolierung von Silacyclopropenen und Silacyclopropanen ist bisher nicht gelungen.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 8 (1969), S. 469-477 
    ISSN: 0570-0833
    Keywords: Silicon ; Silylene ; Silanediyl ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Like carbenes, silylenes are assumed to occur as intermediates in many reactions. A detailed account of the reactivity of the silylenes is given and the reductive and thermolytic methods used for their preparation are discussed. Insertion and interception reactions emphasize the formal relationship between these species and the carbenes. Silacyclopropenes and silacyclopropanes have not, as yet, been isolated.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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