ISSN:
0018-019X
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Steady-state polarization curves, representative of the electrochemical reduction of HCO3- ions at a smooth palladium cathode, obtained in CsHCO3 and NaHCO3 solutions, are compared. The net current densities, associated with the electroreduction of HCO3- anions, measured in 1M CsHCO3 solution are shown to be up to 9 times larger than those observed in 1M NaHCO3 solution. This result is interpreted in terms of a direct involvement of the Cs+ cations in the reaction at the cathode through the formation of ion pairs with the HCO3- anions.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/hlca.19860690313
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