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  • 1
    Electronic Resource
    Electronic Resource
    Water-Soluble Phtalocyanines Containing Aza-Crown Ether SubstituentsDedicated to Professor Michael Hanack on the occasion of his 60th birthday. (1991)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 2531-2536 
    Details
    ISSN: 0009-2940
    Keywords: Aza-crown ethers ; Phthalocyanines, amphiphilic ; Quaternary lutetium bis(phthalocyaninates) ; Quaternerization of acetyl amines ; Lutetium complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A straightforward and generalizable synthesis of metal-free and metal (Ni, Pb, Lu) derivatives of symmetrically tetrasubstituted phthalocyanines derived from 15, 16-dibromo- or -dicyano-2, 3, 6, 7, 8, 9, 11, 12-octahydro-5H-benzo[e][1, 4, 7, 13]tetroxaza-cyclopentadecine (1) is described. Quaternarization of the N-acetyl derivatives 7 in a chloroform/dimethyl sulfate mixture gives phthalocyanines 9 soluble in the pH range of 1 - 13. The electronic spectra of the phthalocyanines in buffered solutions (pH 4, 7, and 10) are examined. Furthermore, the electronic spectra of lutetium bis(phthalocyaninate) 9d in water and in DMSO are compared for the first time.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19911241123
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    A platinum zigzag chain in bis(ethylenediamine)copper(II) bis(oxalato)platinate(II): the crystal structure of [Cu(C2N2H8)2][Pt(C2O4)2] (1976)
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 32 (1976), S. 2983-2986 
    Details
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0567740876009412
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    The crystal structure of tris(oxamide oxime)cobalt(III) trichloride, Co(C2H6N4O2)3Cl3 (1978)
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 34 (1978), S. 3591-3593 
    Details
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0567740878011668
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  • 4
    Electronic Resource
    Electronic Resource
    Electrical properties of monoazacrown ether-substituted phthalocyanines (1992)
    Springer
    Journal of materials science 27 (1992), S. 6183-6186 
    Details
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract D.c. conductivities of polycrystalline monoazacrown ether-substituted phthalocyanines (M=2H, Ni, Zn, Pb, Cu) and diphthalocyanine (M=Lu) are measured as Au-MPc-Au sandwiches to be of the order 10−10–10−12 S m−1. Chemical doping with oxidants (e.g. NOBF4) and enhancing the stacking of planar phthalocyanine moieties through the formation of alkali metal adducts with sodium and potassium ions leads to increase in conductivity of the order 101–102. The low conductivity and the diamagneticity of the bis(phthalocyaninato)-lutetium can be ascribed to the lack of radical nature in LuH(Pc)2. For the a.c. conductivities, lead and lutetium complexes form a group with higher conductivities and the rest show lower conductivity. The conduction activation energies calculated from Arrhenius plots exhibit the lowest value (0.40 eV) for the lutetium compound.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01133768
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  • 5
    Electronic Resource
    Electronic Resource
    Synthesis and complex formation of stereoisomers of 1,3-Diphenyl-2-thioxo-4,5-bis(hydroxyimino)-Imidazoline (1983)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 496 (1983), S. 197-204 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung und Komplexbildung der Stereoisomeren von 1,3-Diphenyl-2-thioxo-4,5-bis-(hydroxyimino)-imidazolinDas neue α-Dioxim, 1,3-Diphenyl-2-thioxo-4,5-bis(hydroxyimino)-imidazolin, DTIH2, wurde synthetisiert. Anti- und amphi-Formen des DTIH2 konnten getrennt werden. Die anti- und amphi-Formen von CuII-, NiII-, CoII- und CoIII-Komplexen wurden isoliert, und es wurde versucht, ihre Strukturen anhand von IR, UV-VIS-Spektren und Elementaranalyse zu bestimmen. Die gegenseitige Umwandlung der anti- und amphi-NiII-Komplexe wurde untersucht.
    Notes: The new α-dioxime, 1,3-diphenyl-2-thioxo-4,5-bis-(hydroxyimino)-imidazoline, DTIH2, has been synthesized. Anti- and amphi-forms of DTIH2 could be separated. The anti- and amphi-forms of CuII, NiII, CoII, and CoIII complexes have been isolated and their structures identified by using IR, UV-Visible and elemental analyses. The interconversion of anti- and amphi-NiII complexes has been studied.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19834960121
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  • 6
    Electronic Resource
    Electronic Resource
    Phthalocyanines as Sensitive Materials for Chemical Sensors (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 10 (1996), S. 557-577 
    Details
    ISSN: 0268-2605
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper provides a review of phthalocyan- ines suitable for the development of chemical sensors. Phthalocyanines may be utilized for different types of chemical sensors, including in particular electronic conductance sensors [such as semiconductive, field-effect transistor (FET), solid-state ionic and capacitance sensors], mass-sensitive sensors utilizing a quartz crystal microbalance (QCM) and surface acoustic-wave (SAW) sensors, and optical sensors. The phthalocyanines used are discussed in terms of their physical and chemical properties, as well as their sensitivity, selectivity and reversibility towards the detection of NO2 and organic solvent vapours. The interaction mechanism between phthalocyanine films and analyte molecules is also discussed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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