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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 10 (1977), S. 681-686 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Concentrations and fluxes of mineral particles were deter-mined in the atmosphere and upper water column for a 27-day period in March/April 1986 at a station in the North Pacific (26 °N, 155 °W) aboard the R/V Moana Wave. Atmospheric sampling was also undertaken from platforms ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 140 (1937), S. 684-685 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] ON the Witwatersrand gold mines, where the Bantu mine labourers work under hot humid conditions, cases of scurvy and sub-scurvy occur with some frequency, despite the fact that the diet provided has been shown to contain adequate amounts of vitamin C (some 20–30 mgm. daily). The explanation ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 677-682 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The transitional behavior of poly(vinylidene fluoride) (PVF2) blends with poly(methyl acrylate) and with poly(ethyl acrylate) was examined by differential thermal analysis and dynamic mechanical testing. Both blend systems were judged to be miscible on the bases of the presence of single, composition dependent glass transitions and of the strong melting point depression of the PVF2 component, Blends of poly(isopropyl acrylate) with poly(vinylidene fluoride) were found to be immiscible. These results suggest that miscibility of the acrylate series depends on a specific attractive interaction between the PVF2 and oxygen within the acrylate and the effect of this interaction is diminished as the hydrocarbon content of the ester is increased.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 1225-1234 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A summary of the transitional behavior of blends containing poly(vinylidene fluoride), PVF2, and various oxygen-containing polymers is presented. These data are used to establish the presence of a single miscible amorphous phase. The depression of the PVF2 melting point in those blends judged to be miscible is analyzed using standard thermodynamic arguments to determine the heats of mixing between the amorphous diluents and the PVF2. These heats of mixing are exothermic indicating the presence of strong interactions between the binary pairs. A comparison between the observed interaction strengths and the dipole moments of the various diluents suggests that the exothermic heats of mixing are the result of strong dipole-dipole interactions. Nearly all the miscible blends with PVF2 show Lower Critical Solution Temperature (LCST) behavior. The direct correlation between the temperature location of this phase instability and the observed interaction strength suggests that the instability is more the result of enthalpic considerations than entropic ones.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 1220-1224 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To further investigate the nature of the specific interaction leading to the miscibility of poly(vinylidene fluoride), PVF2, with certain oxygen containing polymers, blends of PVF2 with poly(ε-caprolactone), PCL, with poly(vinyl methyl ether), PVME, and with poly(vinyl methyl ketone), PVMK, were prepared. PVMK/PVF2 blends were found to be miscible while blends of PVME/PVF2 and PCL/PVF2 were found not to be miscible. These results show that the specific interaction with PVF2 involves mainly the carbonyl group rather than the entire ester group. The relative effectiveness of having this group in the chain or pendant to it is not yet resolved.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 683-686 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of poly(vinylidene fluoride) PVF2, with poly(vinyl acetate), PVAc; with poly(vinyl propionate), PVPr; and with poly(vinyl butyrate), PVBu, were prepared by solution blending. Solutions containing PVF2 with either PVPr or PVBu exhibited phase separation, and it was concluded that neither of these polymers are miscible with PVF2. Phase separation did not occur with solutions containing PVF2 and PVAc. Dried samples of this blend system were subjected to differential thermal analysis, dynamical mechanical testing, and visual observations of their melts. From these results, it was concluded that PVF2 and PVAc are miscible. The detailed results and the structural implications of these observations are discussed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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