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  • 1
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A56 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas-liquid jets injected into fluidized beds of particles/catalyst find applications in many industrial processes. The effective distribution and mixing of the feed droplets with the entrained bed particles is vital in improving the process efficiency. The present study utilizes a sophisticated digital X-ray imaging system to study the internal flow structure of jets injected into fluidized beds. The system is equipped with an X-ray image intensifier (XRII) and optical detectors, which convert the transmitted X-ray photons into digital images of up to 60 frames s-1. The imaging technique provides useful information such as the jet expansion angle and the penetration distance. These are functional quantities in optimizing the performance of feed nozzles, and in modeling the jet-fluidized bed interactions.In this work, the horizontal injection of gas, gas-liquid, and liquid jets into fluidized beds is investigated. The results indicate that the jet expansion (half-angle) is considerably reduced for a gas-liquid jet (5-7 degrees) when compared to that of a gas jet (10-15 degrees). The gas-liquid jet also appears to penetrate more than a gas jet with the same momentum. When a liquid feed is introduced into a fluidized bed of particles, the particles may agglomerate if they are wet-enough to form liquid bridges. Improper feed distribution may be a direct contributor to enhanced agglomeration. In this regard, radio-opaque tracers mixed with the feed liquid are injected to track the formation and the movement of agglomerates. The tracer experiments show that the agglomerates are generated at the end of the jet region, close to its maximum penetration distance. A brief discussion on the modifications required to achieve improved contrast for the acquired images, and the effect of some important X-ray parameters are also included in the present study.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, A26 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Monitoring the fluidization quality represents an operating challenge for many processes in which a liquid is sprayed into a gas-fluidized bed, such as fluid coking, fluid catalytic cracking, gas-phase polymerization, agglomeration and drying. Although the presence of liquid will generally have an adverse effect on fluidization, there are often strong incentives in operating with high liquid loadings. For the fluid coking process, for example, operating at lower reactor temperature increases yield and reduces emissions but increases the bed wetness, which may lead to local zones of poor mixing, local defluidization and a reduction in fluidization quality, compromising the reactor performance and stability. The objective of this study is to develop reliable methods to quantify the effects of liquids on fluidized beds. This study examined several methods to evaluate the fluidization quality. Each method was tested in a 3 m tall column, 0.3 m in diameter. Bed wetness was achieved with an atomized spray of various liquids, spanning a wide range of liquid properties. The introduction of liquid in a fluidized bed may result in the formation of wet agglomerates that settle at the bottom of the bed. The liquid may also spread on the particles, increasing their cohesivity and reducing the bed fluidity. Several experimental methods were developed to characterize the effect of liquids on fluidization. Some methods such as the falling ball velocity or the detection of micro-agglomeration from the entrainment of fine particles, are unaffected by agglomerates and detect only the change in bed fluidity. Other methods, such as deaeration or the determination of bubble size from the TDH, are affected by agglomerate formation and changes in bed fluidity.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, R1 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: This review examines the key features and configurations of short residence time cracking processes from a diverse range of industries that have been developed over the past 25 years. These industries include: bitumen or heavy oil upgrading, biomass pyrolysis, olefin production, catalytic cracking, and coal gasification. Characterization of the gas, liquid, and solid products and feedstock is provided wherever possible. In addition, a description of the source and mechanism of heat transfer, and how the feedstock is brought into contact with and separated from - this source is also given.There is a strong economic incentive for considering short residence time cracking processes. Not only do such processes increase the yields of the more valuable liquid and gaseous products, but more compact designs would also decrease capital costs. Careful control of the vapour residence times appears to be crucial in order to prevent secondary cracking and yet allow for maximum cracking of the feedstock. Rapid and thorough mixing of the feedstock with the heat source, not just creating a uniform dispersion, is also a key design aspect to consider. Finally, rapid and complete separation must also be carefully considered; again, to help control product residence time and avoid secondary cracking but also from a heat balance point of view.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A60 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fluid coking is a non-catalytic process where heavy hydrocarbon feed, sprayed using jets into a fluidized bed reactor, cracks upon contacting hot coke particles and produces valuable volatile fractions. It is estimated that the Alberta tar sands contain 1.7 trillion barrels of oil, equivalent to 35% of the world's crude oil reserves, of which the majority is processed using fluid cokers. Important parameters that affect the yield of fluid cokers include the feed jet stability and therefore its ability to entrain and mix the injected feedstock with the fluidized coke particles. To this purpose, this study investigated the effect of the use of various types of draft tubes, placed downstream of the feed jet to enhance mixing, on solids entrainment and jet stability.Specifically, it has been demonstrated with the use of a gas-liquid and gas-only jet that an optimum distance exists between the nozzle and draft tube for entrainment of solids. For both cases, this optimal distance occurs as the jet touches the draft tube wall. However, for a gas-only jet this occurs at a shorter distances due to the increased angle of expansion. The angles of expansion were confirmed using triboelectric probe measurements. It has also been shown that the shape of the inlet to the draft tube will have an effect on the rate of solids entrainment as will the presence of pulsations in the jet.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A47 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: The biosorption of cadmium metal ions by Saccharomyces cerevisiae and Kluyveromyces fragilis yeast cells was studied under various operating conditions in a batch system using shaker flasks and a 2-L double draft tube fluidized bioreactor system. The effects of key parameters such as solution pH, initial metal concentration, biosorbent concentration, and age of the biosorbent cells were investigated. The experiments were carried out at room temperature and pH values of 3.5, 4.5 and 5.0. Three biosorbent yeast cells concentrations (2.5, 5.0 and 7.5 g dry wt./L) were employed with aqueous solutions having initial cadmium concentrations of 50, 100 and 200 mg/L. The solution pH was found to play a critical role in the biosorption process and the metal uptake increased with an increase in pH value. The optimum pH was found to be 5.0. Also, increasing the metal concentration and decreasing the biosorbent concentration increased the final metal uptake per unit cell mass. At a sufficiently high cadmium concentration of 200 mg/L, the effect of initial metal concentration became the dominant factor, since the metal uptake became constant with respect to the initial metal concentration, regardless of pH value. The results showed that the effect of biosorbent concentration on metal uptake was less significant than those of the cadmium concentration and the pH. It was also found that the younger the yeast biosorbent, the higher the metal uptake capacity. Generally, the cadmium uptake was found to take place rapidly, whereby almost 90% uptake occurred within the first five minutes of exposure. The equilibrium of cadmium biosorption was investigated under the same operating conditions. The Langmuir and the Freundlich adsorption isotherms were used to fit the experimental data. However, both of these conventional adsorption models did not fit the experimental data accurately. The maximum uptake capacity was estimated to be close to 35 and 40 mg Cd/g DW cell for S. cerevisiae and K. fragilis, respectively at a pH value of 5.0.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A51 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Making best use of the Circulating Fluidized Bed (CFB) hydrodynamics is crucial in order to attain optimal yield and selectivity of desirable products in such reactors. While the conventional CFB riser has been proven to be highly effective for fast gas-solid reaction systems, the CFB downer promises further improvements over the CFB riser, due to its more uniform flow and better controlled fluid-solid contact times. To obtain a better understanding of both reactors, individual hydrodynamic models are developed for a downer and a riser. Both hydrodynamic models incorporate parameters that have not been investigated in depth so far. For example, empirical correlations have been developed to estimate the agglomeration within downers and the slip velocity in risers.The simulation results of both models are verified using experimental data that has been collected using a state-of-the-art riser/downer pair. The comparison of downer and riser model predictions reveals that downers operate at higher particle velocities and under more dilute conditions than risers and may therefore be better suited for fast chemical reactions that are run under dilute conditions. The benefit of downers may be extended if the higher solids holdups observed in risers can be attained through improvements in recycling and feeding particles into the downer. Most of the catalyst particles that the feed gas contacts in the downer are at their highest activity levels since the particles move slightly faster than the gas phase due to gravitational effects. Also, in case of catalytic reactions where over-cracking is an issue, the narrow residence time distribution in downers allows for better reaction control that leads to higher rates of desirable products. Therefore, at similar solids concentrations, downers are expected to outperform risers for catalytic reactions.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, S2 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the fluid coking process, bitumen and steam are sprayed into a fluidized bed of coke particles. The liquid reacts on the surface of the hot particles to give distillate products, light gases and coke. A good primary particle/liquid mixing in the spray jet is required in order to achieve high yields of valuable products and minimize operability problems due to particles agglomeration or loss of bed fluidity.An Enhanced Solids Entrainment (ESE) device has been proposed to improve the mixing of droplets and particles during injection. It consists of a cylindrical tube mounted co-axially downstream of the spray nozzle. The objective of this study is to develop an effective and convenient non-invasive technique to quantify the improvements in liquid distribution on the particles that results from the use of ESE device.A slug of 30 vol% ethanol in water solution is sprayed into a fluidized bed of sand. The bed is defluidized shortly after the start of the ethanol water injection. Then, the gas-solid contacting pattern is changed to fixed bed, with downward airflow. The evaporation rate can be obtained from the measured concentration of ethanol in the gaseous effluent. The evaporation rate depends on the wetted area that is exposed to the gas. Good primary dispersion of the liquid on particles yields a large exposed wetted area and, hence, a high evaporation rate. A model is used to estimate the distribution of liquid on the particles from the measured evaporation rate.The experimental results show that the ESE device produces a more uniform primary liquid distribution on the particles, increasing by 7 to 21 % the mass of solids contacted by the injected liquid.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, A22 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method has been developed to predict the horizontal jet penetration of gas-liquid sprays injected into gas-solid fluidized beds. The technique involves combining a theoretical model to predict the momentum flux of two-phase sprays with the Benjelloun et al. (1995) correlation for gas jets. Following this treatment, a generalized version of the jet penetration correlation has been developed, which includes the effect of nozzle geometry. The correlation predictions are in very good agreement with the experimental data for a wide range of nozzle geometries, nozzle scales, and jet fluids.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 5.2007, 1, S4 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Submerged gas jets issuing into fluidized beds are used in many different industries and it is important to have a fundamental understanding of how the gas and surrounding medium interact - to understand the flow patterns and how the solids behave in the vicinity of the nozzle jet. Following the discussions of Bohnet and Teifke (1985) and Idelchek (1994) it was decided to qualitatively investigate the effects of altering the region surrounding the contact between the jet and the fluidized bed. Alteration of the flow pattern was accomplished using a semi-cylindrical shroud (0.035 m i.d. and 0.043 m long) that formed a physical barrier around the nozzle tip. The nozzle inner diameter was 0.0016 m i.d. and the motive gas flow rate was supersonic. Videos were recorded of the solids and gas flow patterns via a special transparent plate on the wall of the fluidized bed for a half-jet with and without a shroud at a superficial fluidization gas velocity of 0.11 m/s. Presented below are the original videos and observations derived from the two simple experiments in a fluidized bed with a rectangular cross-section (0.10 by 1.20 m and 2.0 m high). There was a significant difference in the flow patterns of the solids in the vicinity of the nozzle tip when the shroud was present. Furthermore, the jet expansion angle and penetration were observed to decrease by approximately 50% and 43%, respectively.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 31 (1992), S. 2652-2660 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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