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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 13 (1978), S. 2109-2118 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of particle size ratios on tensile strength, tensile modulus, impact strength, Vickers hardness and transverse rupture strength of particulate PVC-Cu composite has been studied. The strength values reach a maximum at a particular metal loading where the formation of a segregated network is believed to occur. This critical metal loading shifts towards lower values with increasing polymer-to-metal size ratios. The mean free path calculated from the proposed model is found to be same in all metal loadings, corresponding to strength maxima irrespective of the particle size ratios. A correlation between strength properties and the mean free path has been suggested.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 540-544 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Scanning electron microscopy (SEM) studies of fracture surfaces of poly(vinyl chloride) - copper composites at various metal loadings and different processing conditions reveal characteristic features. In general, metallic fillers introduce brittleness, while plasticizers increase the ductility of the composites. Results of the fracture studies have been correlated with the properties of the composites reported earlier.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The presence of additives influences the state of segregation of filler particles in the polymer matrix which in turn controls the electrical and mechanical properties of poly(vinyl chloride)-copper composites. The liquid plasticizer seems to form a coating on the filler surface which introduces quasirandomness in the segregated network. In accordance with the mathematical model proposed earlier, the strength properties were found to be proportional to dm-½ where dm is the mean free path between the filler particles. Calculations of dm were based on two different models, one for segregated network (unplasticized and low plasticized composites) and the other for quasi-random distribution of filler particles (plasticized composites). Extruded samples in general show more randomness in the filler distribution than the compression molded samples.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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