ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Description / Table of Contents:
Atactic poly(2-pyridylethylene) [poly(2-vinylpyridine)] forms with transition metal compounds in ethanol the following complexes:[Mt(II)L2(C7H7N)2]n (1b, 1c), [MtJ2(C7H7N)3]n (2b, 2c), [NiJ2(C7H7N)4]n (3b), [FeCl2(C7H7N)2]n (1a), [CoCl2(C7H7N)3]n (2a) und [FeCl3(C7H7N)2]n (4), Mt = Co, Ni. L = acetylacetonate. The coordination behaviour of poly(2-pyridylethylene) and the IR-spectra are discussed.
Notes:
Ataktisches Poly(2-pyridyläthylen) [Poly(2-vinylpyridin)] bildet mit Übergangsmetallverbindungen in Äthanol die folgenden Komplexe:[Mt(II)L2(C7H7N)2]n (1b, 1c), [MtJ2(C7H7N)3]n (2b, 2c), [NiJ2(C7H7N)4]n (3b), [FeCl2(C7H7N)2]n (1a), [CoCl2(C7H7N)3]n (2a) und [FeCl3(C7H7N)2]n (4), Mt = Co, Ni. L = Acetylacetonat. Das Koordinationsverhalten des Poly(2-pyridyläthylens) und die IR-Spektren werden diskutiert.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1973.021720104
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