ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In the hypoiodite reaction of 20-hydroxy steroids, 17α- and 17β-iodo androstanes are formed as by-products by fragmentation of the intermediate alkoxy radicals. The epimeric iodides show antipodal CD.- and ORD.- curves in accordance with their absolute configuration at the relevant chiral centre C(17).
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19720550206
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