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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 1 (1973), S. 269-274 
    ISSN: 1432-0630
    Keywords: Neodymium YAG ; Fluorescence quenching
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We show that quenching of the Nd fluorescence is in principle not associated with the Nd3+ ion but with the host. The process is due to near-field electric dipole interaction between Nd pairs, and cross relaxation via the4I1 5/2 manifold. We present for the first time the complete fluorescence spectrum and level scheme of Nd∶YAG, and find that Nd∶YAG has an exceptional level configuration which boosts cross relaxation. Our results encourage the search for new Nd laser materials which have a slightly different position of the4I1 5/2 manifold so that higher Nd concentrations can be achieved for integrated-optics applications. Finally, we report on implications of energy migration which we found to be quite effective in Nd∶YAG.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 1 (1973), S. 275-278 
    ISSN: 1432-0630
    Keywords: Neodymium ultraphosphate ; Fluorescence spectrum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We report on the complete fluorescence spectrum (52 transitions) and the full level system of neodymium ultraphosphate (NdUP) single crystals. Below 30 K the actual linewidths are below 0.1 Å indicating that there is one well defined site for all Nd ions which can be expected from a stoichiometric material. The position of the4I1 5/2 manifold does not allow for cross relaxation which explains the relatively long fluorescent lifetime of NdUP in spite of its high Nd-concentration. We find, however, lifetime shortening at high excitation rates which limits the optical gain of NdUP. We also find a very high rate of energy migration in NdUP which leads us to predict spontaneous single frequency oscillation for cw operation near threshold.
    Type of Medium: Electronic Resource
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