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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 1826-1831 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The irreversible isothermal annealing of the as-deposited defects of hydrogenated amorphous silicon, a-Si:H, deposited at room temperature by concentric-electrode radio-frequency glow discharge is studied using dark and photoconductivity, space-charge limited current, and time-of-flight. The photoconductivity increases as a power law of the annealing time with exponent 0.8. The density of states at the Fermi level, measured by space-charge limited current, is inversely proportional to the annealing time. These results are compatible with bimolecular annealing kinetics. The dark conductivity obeys a Meyer–Nelder rule during the isothermal anneal.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 3981-3989 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High-quality, hydrogenated amorphous silicon (a-Si:H) is deposited at room temperature by rf glow discharge at a high deposition rate using a tubular reactor with cylindrical symmetry (concentric-electrode plasma-enhanced chemical vapor deposition, CE-PECVD). Using the novel CE-PECVD design, room-temperature deposition of a-Si:H with growth rates up to 14 A(ring) s−1, low hydrogen concentration ((approximately-less-than)10%), and the bonded hydrogen in the Si-H monohydride configuration, is achieved for the first time using an rf glow-discharge technique. The influence of the deposition parameters (silane flow rate, pressure, and power density) on the growth rate, optical band gap, and silicon-hydrogen bonding configuration, is quantitatively predicted using a deposition mechanism based on the additive contribution of three growth precursors, SiH2, SiH3, and Si2H6, with decreasing sticking coefficients of 0.7, 0.1, and 0.001, respectively. The low hydrogen concentration is due to the enhanced ion bombardment resulting from the concentric electrode design.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 3990-3996 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High band gap, device-quality, hydrogenated amorphous silicon (a-Si:H) was deposited from silane at room temperature using concentric-electrode plasma-enhanced chemical vapor deposition (CE-PECVD). Increasing the flow of silane from 15 to 99 sccm resulted in a continuous increase of the optical band gap, Eopt, from 1.7 to 2.1 eV, and changed the dominant bonding configuration from Si-H to Si-H2. The total hydrogen concentration as determined from the integrated absorption of the SiHx stretching bond increased from 7% to 15%. As Eopt varied between 1.7 and 2.1 eV, the photoconductivity, σph, decreased from 10−5 to 10−7 Ω−1 cm−1 and the dark conductivity, σd, dropped from 10−10 to 10−14 Ω−1 cm−1 (σph and σd measured at room temperature after a 1 h anneal at 200 °C). These results are superior to those obtained using a-SiC:H alloys deposited under comparable conditions (i.e., without hydrogen dilution). After annealing, three different conduction paths were identified and correlate with the silicon-hydrogen bonding configuration. The photosensitivity of high band gap a-Si:H films, σph/σd, follows Slobodin's rule for a-SiGe:H alloys. High band gap a-Si:H deposited by CE-PECVD has significant potential to challenge the role of a-SiC:H as the choice material for films with 1.7 (approximately-less-than) Eopt (approximately-less-than) 2.1 eV.
    Type of Medium: Electronic Resource
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