ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Four types of telomer homologs, corresponding to cleavage of the C-H and C-Cl bonds in the telogen during chain transfer and the formation of the radicals ĊCl3- and ĊHCl2-, carrying the kinetic chain, were identified in the products of radical telomerization of propylene with CHCl3 by the methods of gas-liquid chromatography, mass, IR, NQR, and PMR spectroscopy. 2. The addition of the radicals CCl3[CH2CH(ĊH3)]n with n≥2to propylene proceeds with some stereoregularity and obeys close stereochemical principles with chain transfer by these radicals to CCl4.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00854906
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