Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
84 (1986), S. 584-589
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We have performed an optically detected electron-nuclear double resonance (ODENDOR) study of one of the low-lying triplet excitations in the charge transfer complex anthracene/tetracyanobenzene. The study shows that the spectroscopic characteristics associated with this specific excitation are related to an almost complete charge transfer from anthracene to a nearest neighbor tetracyanobenzene molecule. This photoinduced charge transfer results in a reorientation of the (effectively charged) partners of the EDA complex. The possible impact of this result for the other types of low-lying triplet excitations is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.450604
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