Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 15 (1997), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Chemical disequilibrium exists between all phases of the Alpe Arami garnet-peridotite body (Ticino, Switzerland) which hampers the evaluation of P-T conditions of origin, yet disequilibrium offers the inherent possibility to derive a P-T-t path for this mantle slice. We tried to tackle this problem by carrying out new mineral analyses and taking diffusion rates and bulk-rock compositional effects into consideration. Peak metamorphic conditions from mineral core compositions were estimated as 112050C/50.2 GPa. These values are significantly higher than previously published results and were determined from a combination of the O'Neill & Wood (1979) Fe/Mg garnet-olivine exchange thermometer and the Al-in-orthopyroxene barometer (Brey & Köhler, 1990), and are supported by the Ca/Cr ratios in garnet, which are in accord with these conditions. Details of the exhumation path were derived from (1) rim compositions of minerals that yield a first retrograde stage of 720 50C/2 0.25 GPa (2) a spinel lherzolite assemblage in narrow shear zones (tectonic phase F0″, after Möckel, 1969) which documents a second retrograde stage at 500–600C/0.8-l.5 GPa. The Ca content in olivine (Köhler & Brey, 1989) can be used to evaluate further P-T conditions along the retrograde path. We measured very low values (30–40 ppm Ca) in the cores of olivine and a remarkable increase towards the rim (120 ppm). The low core values may reflect an equilibrium stage during the main Alpine metamorphism. The increasing values towards the olivine rims probably represent a late-stage heating event. The initial cooling rates for the peridotite body are between 2700 and 5100C Ma-1, depending on which diffusion data are used.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A new set of reversal experiments for coexisting ortho- and clinopyroxenes in the system CMAS at conditions between 1,000–1,570° C and 30 to 50 kb is presented and combined with literature data. Pyroxene behaviour, particularly that of clinopyroxene, is very complicated and different styles of Al incorporation into the pyroxene structure for low and high concentrations of Al are indicated, strongly influencing the exchange of the enstatite component between ortho- and clinopyroxene. Thermodynamic modelling of this exchange is problematic because of the large number of unknown coefficients compared to the number of experiments. Thermometry based on such models becomes very dependent on accuracy of experimental data and analyses of small quantities of elements. Despite this complexity very simple empirical thermometric equations are capable of reproducing experimental conditions in the systems CMS and CMAS over a wide range of P, T conditions. We derived the equation $$T^\circ {\text{ C}} = {\text{1,617}} + {\text{287}}{\text{.9}}*{\text{ln }}K_D + 2.933*P$$ which gives a mean error of estimate of 25° C when applied to CMS and CMAS data.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract New experimental data on compositions of garnets in two-pyroxene — garnet assemblages in the system CaO −MgO −Al2O3 −SiO2 (CMAS) are presented for conditions between 1,100 and 1,570° C and 30 to 50 kb. Garnets in these assemblages become less calcic with increasing pressure. Garnet-orthopyroxene barometry (Al-solubility-barometry) pertinent to geobarometry for garnet lherzolites has been evaluated with a set of experimental data covering the range 900 to 1,570° C and 15 to 100 kb. Various formulations of this barometer work well to 75 kb. Phase equilibria are not sufficient to positively verify the thermodynamic validity of any of such models. Empirical garnet-orthopyroxene barometry at least in the system CMAS can be formulated to obtain a pressure estimate without previous temperature estimation (P(kb)=34.4-19.175 1n X Al M1 +17.702 1n X Ca M2 ). The potential application of an analogous garnetclinopyroxene equilibrium is limited because the amount of Ca-Tschermaks in natural clinopyroxenes is usually quite small in garnet lherzolites and many eclogites. The Ca-Mg exchange between garnet and clinopyroxene appears however sufficiently sensitive to pressure to allow calibration of a CMAS barometer. The reaction 3CaMgSi2O6+Mg3Al2Si3O12=3Mg2Si2O6+Ca3Al2Si3O12 has a ΔV o of 3.5 cm3. The total pressure dependency of this reaction is however closer to a theoretical ΔV o of about 5 cm3 when excess volume properties of the phases involved are taken into account. We have calibrated such a barometer (mean error of estimate 2.8 kb) for assemblages with pyrope-rich (py〉80) garnets and orthopyroxenes. This may provide the basis for a geobarometer for eclogites from kimberlites.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 23 (1996), S. 241-241 
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...