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  • 1
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A56 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas-liquid jets injected into fluidized beds of particles/catalyst find applications in many industrial processes. The effective distribution and mixing of the feed droplets with the entrained bed particles is vital in improving the process efficiency. The present study utilizes a sophisticated digital X-ray imaging system to study the internal flow structure of jets injected into fluidized beds. The system is equipped with an X-ray image intensifier (XRII) and optical detectors, which convert the transmitted X-ray photons into digital images of up to 60 frames s-1. The imaging technique provides useful information such as the jet expansion angle and the penetration distance. These are functional quantities in optimizing the performance of feed nozzles, and in modeling the jet-fluidized bed interactions.In this work, the horizontal injection of gas, gas-liquid, and liquid jets into fluidized beds is investigated. The results indicate that the jet expansion (half-angle) is considerably reduced for a gas-liquid jet (5-7 degrees) when compared to that of a gas jet (10-15 degrees). The gas-liquid jet also appears to penetrate more than a gas jet with the same momentum. When a liquid feed is introduced into a fluidized bed of particles, the particles may agglomerate if they are wet-enough to form liquid bridges. Improper feed distribution may be a direct contributor to enhanced agglomeration. In this regard, radio-opaque tracers mixed with the feed liquid are injected to track the formation and the movement of agglomerates. The tracer experiments show that the agglomerates are generated at the end of the jet region, close to its maximum penetration distance. A brief discussion on the modifications required to achieve improved contrast for the acquired images, and the effect of some important X-ray parameters are also included in the present study.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, A26 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Monitoring the fluidization quality represents an operating challenge for many processes in which a liquid is sprayed into a gas-fluidized bed, such as fluid coking, fluid catalytic cracking, gas-phase polymerization, agglomeration and drying. Although the presence of liquid will generally have an adverse effect on fluidization, there are often strong incentives in operating with high liquid loadings. For the fluid coking process, for example, operating at lower reactor temperature increases yield and reduces emissions but increases the bed wetness, which may lead to local zones of poor mixing, local defluidization and a reduction in fluidization quality, compromising the reactor performance and stability. The objective of this study is to develop reliable methods to quantify the effects of liquids on fluidized beds. This study examined several methods to evaluate the fluidization quality. Each method was tested in a 3 m tall column, 0.3 m in diameter. Bed wetness was achieved with an atomized spray of various liquids, spanning a wide range of liquid properties. The introduction of liquid in a fluidized bed may result in the formation of wet agglomerates that settle at the bottom of the bed. The liquid may also spread on the particles, increasing their cohesivity and reducing the bed fluidity. Several experimental methods were developed to characterize the effect of liquids on fluidization. Some methods such as the falling ball velocity or the detection of micro-agglomeration from the entrainment of fine particles, are unaffected by agglomerates and detect only the change in bed fluidity. Other methods, such as deaeration or the determination of bubble size from the TDH, are affected by agglomerate formation and changes in bed fluidity.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, R3 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Discovered in 1991, carbon nanotubes (CNTs) have reached the forefront of many industrial research projects. Carbon nanotubes are tubular carbon molecules with remarkable mechanical, chemical, thermal and electrical properties, which make them useful in various applications. This paper reviews three methods of synthesizing the nanomaterial, namely arc-discharge, laser-ablation and fixed bed/fluidized bed catalytic. These methods have generated a large interest in many industrial companies to date. At the moment, the most critical issue faced by industrial companies is determining the best synthesis method, which will give the most economical large-scale production of CNTs. Compared to the other two methods, the catalytic technique to synthesize CNTs is simple, inexpensive, energy-efficient and can produce large CNTs quantities of high yield and purity.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, R1 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: This review examines the key features and configurations of short residence time cracking processes from a diverse range of industries that have been developed over the past 25 years. These industries include: bitumen or heavy oil upgrading, biomass pyrolysis, olefin production, catalytic cracking, and coal gasification. Characterization of the gas, liquid, and solid products and feedstock is provided wherever possible. In addition, a description of the source and mechanism of heat transfer, and how the feedstock is brought into contact with and separated from - this source is also given.There is a strong economic incentive for considering short residence time cracking processes. Not only do such processes increase the yields of the more valuable liquid and gaseous products, but more compact designs would also decrease capital costs. Careful control of the vapour residence times appears to be crucial in order to prevent secondary cracking and yet allow for maximum cracking of the feedstock. Rapid and thorough mixing of the feedstock with the heat source, not just creating a uniform dispersion, is also a key design aspect to consider. Finally, rapid and complete separation must also be carefully considered; again, to help control product residence time and avoid secondary cracking but also from a heat balance point of view.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A60 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fluid coking is a non-catalytic process where heavy hydrocarbon feed, sprayed using jets into a fluidized bed reactor, cracks upon contacting hot coke particles and produces valuable volatile fractions. It is estimated that the Alberta tar sands contain 1.7 trillion barrels of oil, equivalent to 35% of the world's crude oil reserves, of which the majority is processed using fluid cokers. Important parameters that affect the yield of fluid cokers include the feed jet stability and therefore its ability to entrain and mix the injected feedstock with the fluidized coke particles. To this purpose, this study investigated the effect of the use of various types of draft tubes, placed downstream of the feed jet to enhance mixing, on solids entrainment and jet stability.Specifically, it has been demonstrated with the use of a gas-liquid and gas-only jet that an optimum distance exists between the nozzle and draft tube for entrainment of solids. For both cases, this optimal distance occurs as the jet touches the draft tube wall. However, for a gas-only jet this occurs at a shorter distances due to the increased angle of expansion. The angles of expansion were confirmed using triboelectric probe measurements. It has also been shown that the shape of the inlet to the draft tube will have an effect on the rate of solids entrainment as will the presence of pulsations in the jet.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, A17 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study is concerned with an industrial application involved in the manufacture of the polymer Nylon12, which is polymerised from solid monomer particles. There exists interstitial air among those particles. Oxygen in the air is a strong inhibitor of the polymerization reaction and has to be eliminated from the packed bed of monomer particles before they are introduced into the polymerization reactor. This is done by injecting nitrogen into the packed bed from the bottom of the bed. The nitrogen spreads into the packed bed displacing the air inside. This process is already being employed in the polymer processing industries. The present research focuses on how to make this oxygen elimination process more effective. The information from a parametric study can be used to improve the design and operation of the packed bed to have a more effective oxygen elimination process. Conducting the parametric study numerically saves a lot of time and cost. The numerical model used to simulate the fluid flow in packed beds was successfully validated against experimental and analytical results in previous work. This model is used to carry out a numerical parametric study. It is found that having a single jet at the centre of the packed bed is better than having 4 jets closer to the wall. Having an inclined jet instead of a jet parallel to the wall also improves the oxygen elimination process. Simulations are also done with helium as the carrier gas; though economically, it is better to use nitrogen, the purpose of using helium is to investigate the effect of the properties of the carrier gas on the oxygen elimination process.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 1.2003, 1, A49 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: The core-annulus structure is essential to the modeling and optimization of riser reactors such as used in Fluid Catalytic Cracking. This paper presents results of measurements taken with various probes in a pilot plant and in an industrial riser. The instantaneous probe signals were analyzed with sophisticated signal analysis methods based on the detection of cycles and the determination of the correlation dimension.In a pilot plant riser, a core-annulus structure was identified with optical and momentum probe measurements. Cycle analysis of the optical probe measurements showed that the annulus was unstable: its thickness fluctuated with an average cycle time of 0.3 s. There were waves at the core-annulus boundary. In an industrial riser, a similar core-annulus structure could be identified with temperature and momentum probe measurements. Local temperature measurements are much easier to perform in an industrial riser than momentum probe measurements but can provide, with cycle analysis, the location of the core-annulus transition. Analysis of the momentum probe and temperature signals showed that the thickness of the wavy transition layer between core and annulus was about the same in the pilot plant and the industrial riser, meaning that the relative range of fluctuations in annulus thickness was much smaller in the larger industrial riser.A model was developed to predict the time-averaged transition between core and annulus. This model, which had been successfully used to predict the annulus thickness in dilute-phase vertical pneumatic transport lines, assumes that the annulus thickness is such that the riser pressure drop is minimized. Measurements and model predictions were in good agreement.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, S2 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the fluid coking process, bitumen and steam are sprayed into a fluidized bed of coke particles. The liquid reacts on the surface of the hot particles to give distillate products, light gases and coke. A good primary particle/liquid mixing in the spray jet is required in order to achieve high yields of valuable products and minimize operability problems due to particles agglomeration or loss of bed fluidity.An Enhanced Solids Entrainment (ESE) device has been proposed to improve the mixing of droplets and particles during injection. It consists of a cylindrical tube mounted co-axially downstream of the spray nozzle. The objective of this study is to develop an effective and convenient non-invasive technique to quantify the improvements in liquid distribution on the particles that results from the use of ESE device.A slug of 30 vol% ethanol in water solution is sprayed into a fluidized bed of sand. The bed is defluidized shortly after the start of the ethanol water injection. Then, the gas-solid contacting pattern is changed to fixed bed, with downward airflow. The evaporation rate can be obtained from the measured concentration of ethanol in the gaseous effluent. The evaporation rate depends on the wetted area that is exposed to the gas. Good primary dispersion of the liquid on particles yields a large exposed wetted area and, hence, a high evaporation rate. A model is used to estimate the distribution of liquid on the particles from the measured evaporation rate.The experimental results show that the ESE device produces a more uniform primary liquid distribution on the particles, increasing by 7 to 21 % the mass of solids contacted by the injected liquid.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, A22 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method has been developed to predict the horizontal jet penetration of gas-liquid sprays injected into gas-solid fluidized beds. The technique involves combining a theoretical model to predict the momentum flux of two-phase sprays with the Benjelloun et al. (1995) correlation for gas jets. Following this treatment, a generalized version of the jet penetration correlation has been developed, which includes the effect of nozzle geometry. The correlation predictions are in very good agreement with the experimental data for a wide range of nozzle geometries, nozzle scales, and jet fluids.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 5.2007, 1, S4 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Submerged gas jets issuing into fluidized beds are used in many different industries and it is important to have a fundamental understanding of how the gas and surrounding medium interact - to understand the flow patterns and how the solids behave in the vicinity of the nozzle jet. Following the discussions of Bohnet and Teifke (1985) and Idelchek (1994) it was decided to qualitatively investigate the effects of altering the region surrounding the contact between the jet and the fluidized bed. Alteration of the flow pattern was accomplished using a semi-cylindrical shroud (0.035 m i.d. and 0.043 m long) that formed a physical barrier around the nozzle tip. The nozzle inner diameter was 0.0016 m i.d. and the motive gas flow rate was supersonic. Videos were recorded of the solids and gas flow patterns via a special transparent plate on the wall of the fluidized bed for a half-jet with and without a shroud at a superficial fluidization gas velocity of 0.11 m/s. Presented below are the original videos and observations derived from the two simple experiments in a fluidized bed with a rectangular cross-section (0.10 by 1.20 m and 2.0 m high). There was a significant difference in the flow patterns of the solids in the vicinity of the nozzle tip when the shroud was present. Furthermore, the jet expansion angle and penetration were observed to decrease by approximately 50% and 43%, respectively.
    Type of Medium: Electronic Resource
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