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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 4 (1988), S. 350-354 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 2497-2503 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The encapsulated FENE dumbbell model has been found highly successful to predict the rheological behavior of concentrated polymer solutions and melts. Here we extend the model to apply to nonuniform flows, with particular emphasis on viscometric flows. For the special case of tube flow nonuniform concentration profiles are predicted, which depend crucially upon the model parameters. Though migration to and away from the tube axis is clearly asserted, the final nonuniformity is rather small in either case.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 6437-6441 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The diffusion equation based on the encapsulated FENE model concept is applied to circular Couette flow. In all cases studied, a nonuniform concentration distribution is predicted, decreasing with increasing distance from the inner cylinder. For highly dilute solutions the degree of nonuniformity increases with increasing shear rate and increasing flexibility. For concentrated solutions the data reported in the literature are used. In contrast to earlier tube flow predictions, all the systems studied behave qualitatively in the same way. Up to the limit of vortex formation the theory presented should be valid. The implications of nonuniform concentration profiles for normal stress measurements are outlined.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Continuum mechanics and thermodynamics 4 (1992), S. 137-150 
    ISSN: 1432-0959
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The problem of a dilute polymer solution in equilibrium close to a wall, an edge, and a corner, respectively, is studied theoretically. Detailed knowledge of the rheology in these regions is needed in order to obtain the proper boundary conditions for bulk variables. It is interesting to see that shear stresses are predicted, whose origin is based on the intramolecular (elastic) interaction between the beads.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1432-1114
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this study the slit flow of an electrorheological (ER) fluid in an AC-field is studied with and without obstruction. Non-viscometric flow conditions are attained either by keeping the lengths of the electrodes short or by obstructing the flow via protruding electrodes. This latter condition seems to be beneficial, at least at low volume flow rates and short electrodes.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 267 (1989), S. 627-636 
    ISSN: 1435-1536
    Keywords: Rheology ; surfactantsolutions ; viscosityjump ; timeeffects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper the behavior of an aqueous surfactant solution in a rotational Couette viscometer is investigated. It is shown that this behavior depends strongly upon time, upon the way in which the flow curve is obtained (with increasing or decreasing shear rate), upon the temperature, and upon the concentration of the solution. Furthermore, the results also reveal a pronounced dependence upon the size of the actual measuring system used. It is shown that the slip-velocity concept is not applicable to explain this dependence.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Archive of applied mechanics 61 (1991), S. 119-132 
    ISSN: 1432-0681
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Summary In this paper experimental results for drag reduction in turbulent pipe flows are reported. Drag reduction was achieved by the addition of high molecular weight polymers. The degradation of these polymers (chemically) thermally as well as mechanically was investigated and the effect of stabilizers was studied. Special emphasis is devoted to the effect of temperature on the onset of drag reduction. The influence of pipe diameter and of polymeric concentration on the critical wall shear stress (beyond which drag reduction ceases to exist) is deduced.
    Notes: Übersicht Die vorliegende Arbeit faßt Ergebnisse von experimentellen Untersuchungen zusammen, welehe durchgeführt wurden, um die reibungsmindernde Wirkung von Polymeren quantitativ zu bestimmen. Für die Durchführung der Untersuchungen sind zwei Meßeinrichtungen erstellt worden, die in der Arbeit beschrieben sind. Durch ihren Einsatz gelang es, die reibungsmindernde Wirkung von Polymeradditiven zu bestimmen und ihre mechanische Degradation sowie auch ihre Chemie-verursachte, bei erhöhten Temperaturen beschleunigt auftretende Degradation zu quantifizieren. Es werden theoretische Überlegungen zusammengefaßt, welche die mit einer Temperaturänderung auftretende Variation des Einsatzpunktes der Reibungsminderung zu erläutern erlauben. Messungen der kritischen Schubspannungsgeschwindigkeit werden angegeben, bei deren Überschreitung die reibungsmindernde Wirkung der Polymeradditive reduziert wird. Die experimentell gefundene Abhängigkeit dieser Größe vom Rohrdurchmesser und der Polymerkonzentration der Lösung wird aufgezeigt. Die für den praktischen Einsatz wichtige chemisch-thermische und mechanische Degradation der Reibungsminderung durch Polymeradditive wird quantitativ untersucht. Stabilisierende Zusätze werden hinsichtlich ihrer Wirkung im Rahmen von Meßreihen erfaßt.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 37 (1998), S. 189-194 
    ISSN: 1435-1528
    Keywords: Key words Porous medium flow ; viscous and elastic effects ; flow ; irregularities ; increased resistance ; laser sheet technique
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract In this study the local flow of a polymeric solution inside a porous medium is studied visually. While the flow is quite uniform for low volume flow rates it shows pronounced nonuniformity for higher volume flow rates. That is to say, only certain preferred passages are taken and these passages change in time (they fluctuate). This flow irregularity is the reason for increased resistance.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 37 (1998), S. 566-572 
    ISSN: 1435-1528
    Keywords: Key words Axisymmetric flow ; relative vorticity ; invariants of D ; constitutive equation ; quasi-Newtonian fluid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract In this paper a constitutive equation for the extra stress tensor τ is considered, which can be used for steady axisymmetric flows when u ϕ=0 (non-swirling). It is explicit with coefficients which, in case of incompressibility, depend only upon three invariants. As such it should prove useful in numerical calculations, especially so if used in its simplest form, namely the quasi-Newtonian fluid. Here, a purely viscous code can be used. The constitutive equation is self-consistent and receives additional justification from the fact that any constitutive equation is bound to result in the form proposed if the flow is a constant stretch history flow.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 23 (1984), S. 163-171 
    ISSN: 1435-1528
    Keywords: Polymer solution ; nonuniform flow ; bead spring model macromolecule ; hydrodynamic interaction ; nonuniform concentration profile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The hydrodynamics of bead-spring model macromolecules in nonhomogeneous flows has recently been worked out. By taking a non-infinite distance between the beads (relative to the bead size) into account a hydrodynamic driving force was found. In this paper we explore the kinetic theory consequence of that force and show that non-uniform (polymer) concentration profiles are to be expected in nonhomogeneous flows. The diffusion equation for a dilute polymer solution is derived from the continuity equation for the distribution function. Arguments, leading to a well-ordered pertubation expansion of the continuity equation are advanced and the zeroth order function of this hierarchy is studied for models with linear springs. Details for the channel flow system are worked out with special emphasis on the relation between the polymer concentration and the parameters of the system. Explicit results are presented for models with linear springs. It is shown that if the Oseen tensor is not preaveraged, inadmissible results emerge.
    Type of Medium: Electronic Resource
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