ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Borabenzene Derivatives, VIII: A New Route to Alkalimetal Borinates. Syntheses of Ruthenium, Osmium, Rhodium, and Platinum Compounds with Borinate LigandsDegradation of bis(borinato)cobalt complexes Co(C5H5B — R)2(R = C6H5, CH3) with alkalimetal cyanides MCN (M = Na, K) yields alkalimetal borinates M[C5H5B — R]. These are versatile synthetic intermediates as demonstrated by the syntheses of Ru(C5H5B — R)2 (R = C6H5, CH3), Os(C5H5B — C6H5)2, Rh(1,5-C8H12)(C5H5B — R), and Pt(CH3)3(C5H5B — C6H5).
Notes:
Der Abbau von Bis(borinato)kobalt-Komplexen Co(C5H5B — R)2 (R = C6H5, CH3) mit Alkalimetallcyaniden MCN (M = Na, K) liefert Alkalimetallborinate M[C5H5B — R]. Diese sind vielseitige Synthesezwischenprodukte, wie mit der Darstellung von Ru (C5H5B — R)2 (R = C6H5,CH3), Os(C5H5B — C6H5)2, Rh(1,5-C8H12)(C5H5B — R) und Pt(CH3)3((C5H5B — C6H5) gezeigt wird.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19761090704
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