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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 33 (1994), S. 1889-1896 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, S1 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Recently, we patented an efficient process for the drying of digested sludge with zero liquid emission. The main components of this drying system are a conical spouted bed dryer and a natural gas combustion chamber that burns the Volatile Organic Compounds (VOC) in the drying gases. The proposed integrated spouted bed drying process is simple and safe. It is also robust and easy to maintain since there is no moving mechanical part in the set-up. Although the system is quite thermally efficient, the operating and the investment costs are still relatively high. In order to avoid the combustion chamber and its accessories operating at high temperature and to reduce the energy consumption, a catalytic fluidized bed dryer may replace these units. It is proposed, then, to produce in situ the energy for the drying by catalytic oxidation of hydrocarbons and to destroy catalytically the VOCs generated by the drying. The purpose of this paper is to show the feasibility of this new process, called the catalytic drying of digested sludge. Based on the experimental work, advantages and limitations of this process are also discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 2.2004, 1, R2 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multiphase reactors are often used as petrochemical, biological and pharmaceutical reactors. Understanding the mixing mechanism responsible for phase mixing is necessary for modeling purposes. Phase mixing may considerably affect reactor performance. In the literature, each phase mixing was often described by the Axial Dispersion Model (ADM), without physical justification. Some authors doubted the validity of the ADM and that it could represent the mixing of the phases and instead proposed other models. Also, some authors studied the fundamental mechanism responsible for phase mixing. For conversion and selectivity prediction purposes, the use of more complex phenomenological phase mixing models is essential when the kinetics are rapid and the interfacial mass transfer is limited. Many literature reviews concerning multiphase reactors have been published. These reviews, however, discuss phase mixing modeling based on the ADM and do not deal with the other phase mixing models. The aim of this work is to review the literature on phase mixing modeling, based on a mechanistic approach, for three kinds of multiphase reactors: the bubble column (solid free), slurry bubble column (small/light particles) and three phase fluidized bed (large/heavy particles) reactors. The common feature of these reactors is the presence of gas bubbles, which considerably influence the phase hydrodynamic. Hence, a mixing model proposed for one of these reactors may be conceptually representative of the mixing of the two others.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 5.2007, 1, A3 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of this work was to investigate the relative contribution of the convective and dispersive mixing mechanisms to the overall solid phase mixing mechanism for three-phase fluidized bed reactors. Noninvasive Radioactive Particle Tracking (RPT) data were obtained at various operating conditions, reactor diameters and particle systems. The structural wake model was updated and consists of three sub-phases: the particle wake and downflow-emulsion phase following the convective mixing mechanism and the vortex-emulsion phase following the dispersive mixing mechanism. The particle velocity mean and STD increased with the superficial liquid and gas velocity as well as the reactor diameter for each particle phase. Therefore, the extent of mixing increased under these operating parameters. The particle phase's holdup and a new Mixing Mechanism Indicator (MMI), however, exhibited a much more complex trend. For the larger reactor (Dc = 0.292 m), the convective mixing mechanism dominated and at low superficial liquid velocity the contribution of the convective mixing mechanism increased with superficial gas velocity. This trend, however, was reversed when the superficial liquid velocity increased. For the smaller reactor (Dc = 0.10 m), the random movement of the solid dominated. Therefore, the extent of mixing and the mixing mechanism did not follow the same trend. The CFD and the mixing model have to follow both those hydrodynamic properties. Relations to estimate mean and STD particle velocity distribution as well as particle phase holdup were developed. Solid in the established region mainly followed the convective mixing mechanism. Random movement of the solid was mostly observed at the top of the bed, but it was also present in the established region and at the bed bottom. The volume of each region depended on the operating conditions, reactor diameter and particle system. Furthermore, the particle wake expulsion frequency range was similar to the wake shedding frequency found in literature. It is, thus, possible to assume that wake shedding was mainly responsible for the solid exchange between particle phases.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, A54 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Homogeneous flows of air-water in two bubble columns, 0.130 m and 0.292 m in diameter, were investigated using RPT (radioactive particle tracking) and fibre optics. The homogeneity of bubble flows at U g 〈 0.04 m/s was revealed not only in the hydrodynamics of the gas/liquid phase but also in the transport phenomena (turbulence intensity). RPT Lagrangian data derived that turbulence was about 0.15 m/s for the radial direction and 0.26~0.35 m/s for axial direction in the 0.292 m column, 0.05~0.16 m/s for the radial direction and 0.25~0.35 m/s for the axial direction in the 0.13 column. Average bubble diameter was 4~5.3 mm and was almost constant for the radial locations. The result was twice the sizes of the predicted bubble sizes in the CFD modeling. The slip velocity was 0.3 m/s at U g=0.015~0.033m/s as it was assumed in many reactor designs, and only a small variation was found at the radial locations. In flow patterns, stable circulation cells were revealed using velocity vector plots if a single nozzle sparger was used in the 0.13m column, which confirmed Joshi's assumptions (Joshi and Sharma, 1979) and Lin's assumption (Lin et al., 1996) based on 2-D columns. Using a perforated sparger was helpful to form a stable mean velocity field. Mean bubble diameters and bubble size distribution varied only slightly with radial/axial locations, which was consistent with the homogeneity of radial/axial turbulence. Bubble-size evolution from their formation to equilibrium mean diameter was discussed. Mean bubble size correlation was approached. The homogeneity of investigated flows was also substantiated by the criteria of stability for bubble flows.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, A18 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Industrial history is full of events related to scale-up challenges. Failure at the scale-up stage is no longer surprising. Engineers and scientists have been trying to gather all the key parameters for decades, but, unfortunately, there are still no exact and well-established rules ensuring an accurate transition from one scale to another. Even the minimum lab-scale fluidized bed is still undefined. In this work, the effect of bed diameter on gas-solid behavior is investigated in three fluidized beds, 152mm, 78mm, and 50mm in diameter, in which the conventional scale-up rules are respected. The experiments were carried out using sand and alumina particles. The results were obtained and confirmed using fiber optic techniques and radioactive particle tracking, respectively. The results show that radial solid hold-up behavior on a small bed diameter scale is completely different from that on the intermediate bed diameter scale. The radial profile of solid hold-up on a small and very small bed diameter indicates an increase from a low value near the wall to a high value at the center at different heights from the distributor. By contrast, the opposite profile is observed on the intermediate bed diameter, similar to what is usually reported in the literature.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, A16 
    ISSN: 1542-6580
    Source: Berkeley Electronic Press Academic Journals
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Solid mixing in fluidized bed reactors has a great impact on the transport phenomena in the reactor. Most studies, concerning solid behavior and hydrodynamic correlations of fluidized bed reactors, have been done at ambient temperature. Industrially, however, fluidized bed reactors operate at high temperatures. The lack of studies at higher temperatures is due to difficulties associated with measuring techniques under these conditions. In extrapolating hydrodynamic parameters derived at ambient temperature to higher temperatures, only the physical property changes of gas and solid phases, such as density and viscosity are taken into consideration. On a microscopic scale, however, change of temperature strongly affects the interaction between particles, which in turn has a substantial impact on the hydrodynamics of a fluidized bed. In this study and for the first time, the Radioactive Particle Tracking (RPT) is used to investigate the effect of temperature on the fluidization of silica sand particles (Geldat-B) in a bubbling fluidized bed reactor. Experiments have been carried out at different temperatures (25-400oC) and superficial gas velocities (0.17-0.75 m/s). The effect of temperature on the global mixing is studied in conjunction with the changes found in the dynamic of the ascending and descending phases. A two-phase countercurrent back-mixing model (CCBM) was used to investigate global solid mixing at different temperatures. The wake exchange coefficient, in the CCBM model, is calculated and compared with the values obtained from different correlations. For various experiments, the exchange coefficient is found to be in the range of 0.6-1.7 sec-1. The correlations can predict the trend of the wake exchange coefficient change with temperature, but they all overestimate it. The correlations developed by Hoffmann et al. (1993) and Lim et al. (1993) were found to give a better agreement with the results at high temperatures.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 31 (1992), S. 2652-2660 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 34 (1995), S. 2971-2980 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 439-443 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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