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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Soft x-ray magnetic circular dichroism (SXMCD) of the L2 and L3 edges is used to independently determine magnetic information for single crystal FexCo1−x alloy thin films (0≤x≤1) grown on ZnSe(001). Similar to surface magneto-optical Kerr effect (SMOKE) but with element and site specificity, SXMCD, which is the difference between the absorption of left and right circularly polarized soft x rays, can be used to determine a variety of magnetic parameters including spin-orbit and exchange interaction energies. Measurements made at the National Synchrotron Light Source (NSLS) U4B beamline on the Fe–Co alloy system exhibit unique changes in SXMCD signal as a function of alloy concentration. The SXMCD signal is found to rise linearly with reducing atomic concentration for both the Co and Fe. At the dilute limit of 10% FE (x=0.1), the Fe L3 SXMCD is found to increase by almost a factor of three to near 40%. In some Fe/Co structures, the largest reported SXMCD values in excess of 70% are observed! This example shows the utility of SXMCD in obtaining magnetic information in alloy systems in an element specific and even site specific manner.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6204-6206 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic structure of Cr films deposited on single crystal Fe(001)/GaAs(001) substrates is investigated by soft x-ray magnetic circular dichroism (SXMCD) of the L2 and L3 absorption edges. We find that 0.25 ML Cr coverages result in Cr moments aligned with each other and antialigned to the underlying Fe moment direction. The Cr moment is measured to be 0.6±0.2 μB. Additional Cr deposition results in a monotonically reducing averaged moment consistent with the island growth of ferromagnetic Cr sheets of a single layer, antialigned with adjoining sheets. SXMCD measurements of the trilayer structures clearly show the antiferromagnetic coupling of the two Fe films through the interlying Cr film.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The element specific magnetic moments of Gd and Fe in a gadolinium iron garnet (Gd3Fe5O12) were probed at various temperatures by measuring the soft-x-ray magnetic circular dichroism (SXMCD) at the Gd M4,5 and the Fe L2,3 adsorption edges in an external field of 5 kG. The soft-x-ray absorption spectra were recorded with the photocurrent method using highly circularly polarized soft x rays recently obtained at the AT&T Bell Laboratories Dragon synchrotron radiation beamline.1 The temperature dependence of the SXMCD signal at each edge allows one to independently determine the magnetic ordering of each specific ion. Our individually probed magnetic moment of the Gd3+ ion and of the two Fe3+ ions in different sites confirm the earlier calculations which predict a reversal of the local magnetic orientation at ∼280 K. This work demonstrates that SXMCD is a valuable tool for probing the element and site specific magnetic properties of multicomponent systems. The applications of this novel technique to the investigation of transition metals and rare earths in ferromagnetic alloys, compounds, disordered, and impurity systems will be addressed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6884-6884 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Recent developments in synchrotron radiation instrumentation have made possible the production of high quality circularly polarized light in the soft x-ray region (150–1500 eV).1,2 Magnetic circular dichroism (MCD), the difference in the absorption intensity of magnetic systems using left- and right-circularly polarized light, has been exploited in the visible, VUV, and hard x-ray spectral regions to provide valuable information on the electronic and magnetic properties of magnetically oriented systems. Soft x-ray magnetic circular dichroism (SXMCD) has several advantages over the VUV and hard x-ray spectral regions: the major electronic states that are responsible for magnetism, i.e., the 3d states of transition metals and the 4f states of rare-earth elements, can be reached via strong dipole transitions from their respective well-separated 2p3/2, 2p1/2, and 3d5/2, 3d3/2 sharp core levels. Compared to MCD in the visible region, known as the magneto-optical Kerr effect, SXMCD offers element and site specificity with relatively easier data interpretation. A brief review of the principles of SXMCD2 and current instrumental developments will be given. SXMCD measurements conducted at the Dragon beamline on a wide variety of magnetic systems, including transition metals, surfaces, ultrathin films, alloys, ferrites, rare-earth compounds, and biological samples will be utilized to demonstrate the capability of SXMCD as a tool for basic and applied magnetism research.2,3
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic properties of MBE-grown ultrathin Ni films on a Cu(001) substrate are investigated using soft-x-ray magnetic circular dichroism (SXMCD) spectroscopic technique. These measurements are carried out by recording Ni L2,3 absorption spectra with highly circularly polarized soft x rays recently obtained at the AT&T Bell Laboratories Dragon synchrotron radiation beamline.1 For low Ni coverages, no MCD effect along the 〈100〉 direction is observed at room temperature, while for intermediate coverages, the MCD effect becomes appreciable and increases to its bulk value at ∼25 ML. With only the assumption that the unoccupied density of states of Ni lie mainly in the minority bands, the amount of the MCD effect can be related to the magnetic moment. The thickness and temperature dependence of the magnetic moment obtained from our SXMCD measurements are compared with those of Ni/Cu(111) obtained from magneto-optical data.2 The advantages and differences between the SXMCD and MOKE techniques are discussed. The novel SXMCD technique allows for element specific magnetic characterization of a variety of interesting structural architectures including 2 D films, dilute impurities, and disordered matrices.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 5925-5933 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The polarized absorption spectra of oriented films of phase-I and phase-II poly(di-n-hexylsilane), PDHS, have been determined in the visible/UV and in the near-edge regions of the C 1s and Si 1s x-ray ionization potentials. The phase-I absorption band at 360 nm is strongly polarized parallel to the direction of the Si chain, whereas the analog of this band in phase II (317 nm) is only weakly polarized in the same direction; this is consistent with partial trans→gauche isomerization of the Si chain in phase II and delocalization of the excitation in part onto disordered n-hexyl groups. Polarized absorption in the vicinity of the Si 1s ionization limit reveals strong polarization of the discrete and continuum transitions in both phase I and phase II, whereas the equivalent spectra taken in the vicinity of the C 1s limit show strong polarization in phase I but little or no polarization in phase II. The x-ray spectra are interpreted as showing that the Si chain and the n-hexyl groups of the polymer are ordered in phase I and are essentially perpendicular to one another, whereas in phase II the n-hexyl chains are disordered while the Si backbone remains relatively fixed in space. The Si 1s electron-yield spectra also display EXAFS interferences which have been transformed to yield Si–Si and Si–C distances in the polymer of 2.37±0.02 and 1.81±0.03 A(ring), respectively. The various discrete and continuum transitions are assigned according to an orbital model, and the visible/UV thermochromism earlier reported for PDHS is now observed in the Si 1s x-ray near-edge spectrum as well.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 1229-1233 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The raytracing of the double-headed Dragon, a recently proposed monochromator for producing two simultaneous left and right circularly polarized soft x-ray beams, is presented. The energy resolution and wavelength of these two beams are confirmed to be identical, and the high performance of the original Dragon is found to be preserved in the double-headed configuration. A compact ultra-high vacuum compatible chopper for rapid alternation between left and right helicities is presented, and a guideline for collecting circularly polarized light from bending magnet sources is given.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 77 (1955), S. 3415-3416 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 93 (1971), S. 5922-5922 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 77 (1955), S. 2557-2559 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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